Supramolecular Photochirogenesis with Biomolecules. Mechanistic Studies on the Enantiodifferentiation for the Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Bovine Serum Albumin

Photophysics and photochemistry of 2-anthracenecarboxylate (AC) bound to bovine serum albumin (BSA) were investigated in detail for the first time by electronic absorption, circular dichroism (CD), steady-state and time-resolved fluorescence, fluorescence quenching, and product analysis studies. Thr...

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Veröffentlicht in:	Journal of organic chemistry 2007-04, Vol.72 (8), p.2707-2715
Hauptverfasser:	Nishijima, Masaki, Pace, Tamara C. S, Nakamura, Asao, Mori, Tadashi, Wada, Takehiko, Bohne, Cornelia, Inoue, Yoshihisa
Format:	Artikel
Sprache:	eng
Schlagworte:	Animals Anthracenes - chemistry Anthracenes - metabolism Binding Sites Carboxylic Acids - chemistry Carboxylic Acids - metabolism Cattle Chemistry Circular Dichroism Condensed benzenic and aromatic compounds Cyclization Dimerization Exact sciences and technology Fluorescence General and physical chemistry Kinetics and mechanisms Organic chemistry Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Preparations and properties Protein Binding Reactivity and mechanisms Serum Albumin, Bovine - pharmacology Spectrometry, Fluorescence Stereoisomerism
Online-Zugang:	Volltext
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