A square-planar Ni(II) complex with an asymmetric coordination of a novel polynucleative 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand
The title compound, (2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone}(2-))nickel(II) dimethyl sulfoxide solvate monohydrate, [Ni(C(15)H(17)N(7)O(4))] x C(2)H(6)OS x H(2)O, represents the first example of square-planar N(4) coordination via N atoms with four different functions, namely...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2008-03, Vol.64 (Pt 3), p.m137-m139 |
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| container_issue | Pt 3 |
| container_start_page | m137 |
| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 64 |
| creator | Plutenko, Maxym V Moroz, Yurii S Sliva, Tetyana Yu Haukka, Matti Fritsky, Igor O |
| description | The title compound, (2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone}(2-))nickel(II) dimethyl sulfoxide solvate monohydrate, [Ni(C(15)H(17)N(7)O(4))] x C(2)H(6)OS x H(2)O, represents the first example of square-planar N(4) coordination via N atoms with four different functions, namely amide, azomethine, hydroxyimino and pyridine. The coordination polyhedron of the central Ni atom has a slightly distorted square-planar geometry. The 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand forms one six- and two five-membered chelate rings, and a pseudo-chelate ring through an intramolecular hydrogen bond with an amide group as donor and a deprotonated hydroxyimino group as acceptor, resulting in a pseudomacrocyclic arrangement. |
| doi_str_mv | 10.1107/S0108270108003065 |
| format | Article |
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The coordination polyhedron of the central Ni atom has a slightly distorted square-planar geometry. The 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand forms one six- and two five-membered chelate rings, and a pseudo-chelate ring through an intramolecular hydrogen bond with an amide group as donor and a deprotonated hydroxyimino group as acceptor, resulting in a pseudomacrocyclic arrangement.</description><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270108003065</identifier><identifier>PMID: 18322326</identifier><language>eng</language><publisher>United States</publisher><subject>Crystallography, X-Ray ; Hydrogen Bonding ; Ligands ; Models, Molecular ; Molecular Structure ; Nickel - chemistry ; Organometallic Compounds - chemistry ; Stereoisomerism</subject><ispartof>Acta crystallographica. 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The 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand forms one six- and two five-membered chelate rings, and a pseudo-chelate ring through an intramolecular hydrogen bond with an amide group as donor and a deprotonated hydroxyimino group as acceptor, resulting in a pseudomacrocyclic arrangement.</description><subject>Crystallography, X-Ray</subject><subject>Hydrogen Bonding</subject><subject>Ligands</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>Nickel - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><subject>Stereoisomerism</subject><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo1UNFK5TAQDYKoe90P8EXytChYN02atH0U2dULog_et0Uu02SqkTSpSatW8Vf2W62oLzPDOWeGOYeQvZwd5zkrf1-znFW8_KiMCabkBtnJFWOZLGW9TX6kdM8Y45yLLbKdV2IeuNoh_09oehghYtY78BDppT1YLg-pDl3v8Jk-2eGOgqeQpq7DIVo9UyEa62GwwdPQUqA-PKKjfXCTH7XDmXlEyo9UZixoHCbXT9HOK0gbm17_8ezgbjIxPE-2sz4c9jH04MPkbj5geAke36izt-DNLtlswSX8-dUXZPX3z-r0PLu4OluenlxkvSxUVhmp69l2iXktJAgplKxZIYRqqqauWl1BAY1pgQmtWyPyErEuuKpbVqrGFGJBfn2enV95GDEN684mjW6OBMOY1iUTJVeSz8L9L-HYdGjWfbQdxGn9Hah4B-o8eac</recordid><startdate>200803</startdate><enddate>200803</enddate><creator>Plutenko, Maxym V</creator><creator>Moroz, Yurii S</creator><creator>Sliva, Tetyana Yu</creator><creator>Haukka, Matti</creator><creator>Fritsky, Igor O</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>200803</creationdate><title>A square-planar Ni(II) complex with an asymmetric coordination of a novel polynucleative 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand</title><author>Plutenko, Maxym V ; Moroz, Yurii S ; Sliva, Tetyana Yu ; Haukka, Matti ; Fritsky, Igor O</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p546-8d5c98007e1935a35365904336b8b98fc8a4abdfa03ccfd317ee94269f076bd43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Crystallography, X-Ray</topic><topic>Hydrogen Bonding</topic><topic>Ligands</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>Nickel - chemistry</topic><topic>Organometallic Compounds - chemistry</topic><topic>Stereoisomerism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Plutenko, Maxym V</creatorcontrib><creatorcontrib>Moroz, Yurii S</creatorcontrib><creatorcontrib>Sliva, Tetyana Yu</creatorcontrib><creatorcontrib>Haukka, Matti</creatorcontrib><creatorcontrib>Fritsky, Igor O</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Plutenko, Maxym V</au><au>Moroz, Yurii S</au><au>Sliva, Tetyana Yu</au><au>Haukka, Matti</au><au>Fritsky, Igor O</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A square-planar Ni(II) complex with an asymmetric coordination of a novel polynucleative 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Crystallogr C</addtitle><date>2008-03</date><risdate>2008</risdate><volume>64</volume><issue>Pt 3</issue><spage>m137</spage><epage>m139</epage><pages>m137-m139</pages><eissn>1600-5759</eissn><abstract>The title compound, (2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone}(2-))nickel(II) dimethyl sulfoxide solvate monohydrate, [Ni(C(15)H(17)N(7)O(4))] x C(2)H(6)OS x H(2)O, represents the first example of square-planar N(4) coordination via N atoms with four different functions, namely amide, azomethine, hydroxyimino and pyridine. The coordination polyhedron of the central Ni atom has a slightly distorted square-planar geometry. The 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand forms one six- and two five-membered chelate rings, and a pseudo-chelate ring through an intramolecular hydrogen bond with an amide group as donor and a deprotonated hydroxyimino group as acceptor, resulting in a pseudomacrocyclic arrangement.</abstract><cop>United States</cop><pmid>18322326</pmid><doi>10.1107/S0108270108003065</doi></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1600-5759 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2008-03, Vol.64 (Pt 3), p.m137-m139 |
| issn | 1600-5759 |
| language | eng |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | Crystallography, X-Ray Hydrogen Bonding Ligands Models, Molecular Molecular Structure Nickel - chemistry Organometallic Compounds - chemistry Stereoisomerism |
| title | A square-planar Ni(II) complex with an asymmetric coordination of a novel polynucleative 2,6-diacetylpyridine bis{[2-(hydroxyimino)propanoyl]hydrazone} ligand |
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