Bonding Rearrangements of Hydrogen-Bonded Complexes Involving Alkynes
Molecules containing a C−C triple bond, such as HC⋮CH, FC⋮CF, and the C⋮CH radical, are allowed to interact with a partner molecule of H2O, NH3, or HF. Quantum chemical calculations show that these C⋮CH···X H-bonded complexes are bound by up to 4 kcal·mol-1. More importantly, they can rearrange in s...
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| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2008-03, Vol.112 (9), p.1940-1945 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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