Directed 1D Assembly of a Ring-Shaped Inorganic Nanocluster Templated by an Organic Rigid-Rod Molecule: An Inorganic/Organic Polypseudorotaxane

Facing up to matters: Template‐assisted cofacial assembly of a ring‐shaped polyoxomolybdate cluster (MC) by an oligomeric p‐phenylenebutadiynylene rigid rod molecule bearing ammonium ion pendant groups (PBn) allowed for the formation of an inorganic/organic one‐dimensional (1D) nanoobject. Studies i...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-02, Vol.47 (11), p.2070-2073
Hauptverfasser:	Alam, Md. Akhtarul, Kim, Yeong-Sang, Ogawa, Saho, Tsuda, Akihiko, Ishii, Noriyuki, Aida, Takuzo
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene - analogs & derivatives Acetylene - chemical synthesis Acetylene - chemistry Benzene Derivatives - chemical synthesis Benzene Derivatives - chemistry Models, Molecular Molecular Structure Molybdenum - chemistry Nanostructures - chemistry organic-inorganic hybrid composites Oxides - chemistry Particle Size Polymers - chemistry polyoxometalates polypseudorotaxanes Rotaxanes - chemistry supramolecular chemistry Surface Properties transmission electron microscopy
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Beschreibung
Zusammenfassung:	Facing up to matters: Template‐assisted cofacial assembly of a ring‐shaped polyoxomolybdate cluster (MC) by an oligomeric p‐phenylenebutadiynylene rigid rod molecule bearing ammonium ion pendant groups (PBn) allowed for the formation of an inorganic/organic one‐dimensional (1D) nanoobject. Studies indicate that the 1D object most likely has a polypseudorotaxane structure (see picture), in which multiple MC rings are threaded by the PBn rod.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200705308