Formation of Carbanions Using Neutral Organic Molecules as Electron-Transfer Reagents: A Radical Concept

A new generation of organic compounds (see examples) have been developed and used as single‐ and double‐electron donors. Aryl halides and sulfones can be reduced, and using one particular electron donor, aryl anions can be formed. Up until now these reactions were mainly carried out by metals.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-02, Vol.47 (10), p.1819-1823
Hauptverfasser:	McGlacken, Gerard P, Khan, Tanweer A
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Alkynes - chemistry anions Cyclization electron transfer Electron Transport Free Radicals - chemistry Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Indicators and Reagents Ketones - chemistry Molecular Structure radical reactions reduction Sulfones - chemistry synthetic methods
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Beschreibung
Zusammenfassung:	A new generation of organic compounds (see examples) have been developed and used as single‐ and double‐electron donors. Aryl halides and sulfones can be reduced, and using one particular electron donor, aryl anions can be formed. Up until now these reactions were mainly carried out by metals.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200704883