Stabilization of Unsymmetrically Annelated Imidazol-2-ylidenes with Respect to Their Higher Group 14 Homologues by n-/π-HOMO Inversion

From annelation to an elation: The surprising stability of pyridoannelated imidazol‐2‐ylidenes (see scheme) in comparison with the heavier Group 14 homologues suggests broad tuning potential and control of the reactivity by the lone pair of electrons at the carbon atom. The asymmetric distribution o...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2007-01, Vol.46 (15), p.2697-2700
Hauptverfasser:	Ullah, Farman, Bajor, Gabor, Veszprémi, Tamas, Jones, Peter G., Heinicke, Joachim W.
Format:	Artikel
Sprache:	eng
Schlagworte:	carbenes electronic structure Electrons Hydrocarbons - chemistry Imidazoles - chemistry imidazolium Methane - analogs & derivatives Methane - chemistry Molecular Structure photoelectron spectroscopy Silanes - chemistry silylenes Spectrum Analysis
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!