Explanation of the unusual peak of calorimetric heat in the adsorption of nitrogen, argon and methane on graphitized thermal carbon black

Heats of adsorption and adsorption isotherms of argon, nitrogen and methane on a perfect graphitic surface and a defective graphitic surface are studied with a Grand Canonical Monte Carlo Simulation (GCMC). For the perfect surface, the isosteric heat versus loading shows a typical pattern of adsorpt...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2008-01, Vol.10 (8), p.1106-1113
Hauptverfasser: WONGKOBLAP, Atichat, DO, Duong D, NICHOLSON, David
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Sprache:eng
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