Molecular switch based on a cucurbit[6]uril containing bistable [3]rotaxane

Molecular switch based on a cucurbit[6]uril containing bistable [3]rotaxane

A bistable CB6-based [3]rotaxane with two recognition sites has been prepared very efficiently in a high yield synthesis through CB6 catalyzed 1,3-dipolar cycloaddition; this rotaxane behaves as a reversible molecular switch and exhibits conformational changes caused by the movement of rings under b...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (13), p.1369-1371
Hauptverfasser: Tuncel, Dönüs, Ozsar, Ozgür, Tiftik, H Burak, Salih, Bekir
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creator Tuncel, Dönüs
Ozsar, Ozgür
Tiftik, H Burak
Salih, Bekir
description A bistable CB6-based [3]rotaxane with two recognition sites has been prepared very efficiently in a high yield synthesis through CB6 catalyzed 1,3-dipolar cycloaddition; this rotaxane behaves as a reversible molecular switch and exhibits conformational changes caused by the movement of rings under base, acid and heat stimuli from one location to the other.
doi_str_mv 10.1039/b616764k
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title Molecular switch based on a cucurbit[6]uril containing bistable [3]rotaxane
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