Fabrication of Metal Nanowires in Carbon Nanotubes via Versatile Nano-Template Reaction
A nano-template reaction has been developed to fabricate metal nanowires using metallofullerene nanopeapods (i.e., carbon nanotubes (CNTs) encapsulating endohedral metallofullerenes) as starting materials. In this nanometer-scale reaction, the structure of resulting products should possess specific...
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| Veröffentlicht in: | Nano letters 2008-02, Vol.8 (2), p.693-699 |
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| creator | Kitaura, Ryo Imazu, Naoki Kobayashi, Keita Shinohara, Hisanori |
| description | A nano-template reaction has been developed to fabricate metal nanowires using metallofullerene nanopeapods (i.e., carbon nanotubes (CNTs) encapsulating endohedral metallofullerenes) as starting materials. In this nanometer-scale reaction, the structure of resulting products should possess specific low-dimensional structures, because of their uniform starting orientation of metallofullerene molecules and the rigid restriction of reaction space by the presence of walls of CNTs. Using the nano-template reaction, we have fabricated various Gd nanowires, including a single Gd atomic chain, a one-dimensional alignment of Gd squares, and Gd nanowires that correspond to a one-dimensional segment of the bulk close-packed structure. The same reaction, in principle, can be applied to fabricate more than 20 different types of metal nanowires in the CNTs, which simply are dependent on the use of the corresponding different types of metallofullerenes as encapsulates in the CNTs. The present novel reaction will provide a wide variety of unusual low-dimensional nanowires and nanomaterials in the CNTs, which have not been synthesized via the fabrication techniques that have been reported so far. |
| doi_str_mv | 10.1021/nl073070d |
| format | Article |
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In this nanometer-scale reaction, the structure of resulting products should possess specific low-dimensional structures, because of their uniform starting orientation of metallofullerene molecules and the rigid restriction of reaction space by the presence of walls of CNTs. Using the nano-template reaction, we have fabricated various Gd nanowires, including a single Gd atomic chain, a one-dimensional alignment of Gd squares, and Gd nanowires that correspond to a one-dimensional segment of the bulk close-packed structure. The same reaction, in principle, can be applied to fabricate more than 20 different types of metal nanowires in the CNTs, which simply are dependent on the use of the corresponding different types of metallofullerenes as encapsulates in the CNTs. The present novel reaction will provide a wide variety of unusual low-dimensional nanowires and nanomaterials in the CNTs, which have not been synthesized via the fabrication techniques that have been reported so far.</description><identifier>ISSN: 1530-6984</identifier><identifier>EISSN: 1530-6992</identifier><identifier>DOI: 10.1021/nl073070d</identifier><identifier>PMID: 18269254</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemical synthesis methods ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Crystallization - methods ; Exact sciences and technology ; Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties ; Macromolecular Substances - chemistry ; Materials science ; Materials Testing ; Metals - chemistry ; Methods of nanofabrication ; Molecular Conformation ; Nanocrystalline materials ; Nanoscale materials and structures: fabrication and characterization ; Nanotechnology - methods ; Nanotubes ; Nanotubes, Carbon - chemistry ; Nanotubes, Carbon - ultrastructure ; Particle Size ; Physics ; Surface Properties ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><ispartof>Nano letters, 2008-02, Vol.8 (2), p.693-699</ispartof><rights>Copyright © 2008 American Chemical Society</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a409t-7248f33dc332844e1c95257c9a7591691b0ab750cc420e4faafdb1f451b1c9b83</citedby><cites>FETCH-LOGICAL-a409t-7248f33dc332844e1c95257c9a7591691b0ab750cc420e4faafdb1f451b1c9b83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/nl073070d$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/nl073070d$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20110087$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18269254$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kitaura, Ryo</creatorcontrib><creatorcontrib>Imazu, Naoki</creatorcontrib><creatorcontrib>Kobayashi, Keita</creatorcontrib><creatorcontrib>Shinohara, Hisanori</creatorcontrib><title>Fabrication of Metal Nanowires in Carbon Nanotubes via Versatile Nano-Template Reaction</title><title>Nano letters</title><addtitle>Nano Lett</addtitle><description>A nano-template reaction has been developed to fabricate metal nanowires using metallofullerene nanopeapods (i.e., carbon nanotubes (CNTs) encapsulating endohedral metallofullerenes) as starting materials. In this nanometer-scale reaction, the structure of resulting products should possess specific low-dimensional structures, because of their uniform starting orientation of metallofullerene molecules and the rigid restriction of reaction space by the presence of walls of CNTs. Using the nano-template reaction, we have fabricated various Gd nanowires, including a single Gd atomic chain, a one-dimensional alignment of Gd squares, and Gd nanowires that correspond to a one-dimensional segment of the bulk close-packed structure. The same reaction, in principle, can be applied to fabricate more than 20 different types of metal nanowires in the CNTs, which simply are dependent on the use of the corresponding different types of metallofullerenes as encapsulates in the CNTs. The present novel reaction will provide a wide variety of unusual low-dimensional nanowires and nanomaterials in the CNTs, which have not been synthesized via the fabrication techniques that have been reported so far.</description><subject>Chemical synthesis methods</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Crystallization - methods</subject><subject>Exact sciences and technology</subject><subject>Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties</subject><subject>Macromolecular Substances - chemistry</subject><subject>Materials science</subject><subject>Materials Testing</subject><subject>Metals - chemistry</subject><subject>Methods of nanofabrication</subject><subject>Molecular Conformation</subject><subject>Nanocrystalline materials</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>Nanotechnology - methods</subject><subject>Nanotubes</subject><subject>Nanotubes, Carbon - chemistry</subject><subject>Nanotubes, Carbon - ultrastructure</subject><subject>Particle Size</subject><subject>Physics</subject><subject>Surface Properties</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkMtKw0AUhgdRbK0ufAHJRsFF9MytySylWBW8gFRdhjOTCaTkUmcSxbd3akO7cXWGf77zH_gIOaVwRYHR66aChEMC-R4ZU8khnirF9rfvVIzIkfdLAFBcwiEZ0ZRNFZNiTD7mqF1psCvbJmqL6Ml2WEXP2LTfpbM-Kptohk6Hz3XW9TpkXyVG79b5sFTZvzxe2HpVYWejV4tm3XVMDgqsvD0Z5oS8zW8Xs_v48eXuYXbzGKMA1cUJE2nBeW44Z6kQlholmUyMwkQqOlVUA-pEgjGCgRUFYpFrWghJdUB1yifkYtO7cu1nb32X1aU3tqqwsW3vswSYYgAigJcb0LjWe2eLbOXKGt1PRiFbW8y2FgN7NpT2urb5jhy0BeB8ANAbrAqHjSn9lmNAKUCa7Dg0Plu2vWuCi38O_gLq4YUN</recordid><startdate>20080201</startdate><enddate>20080201</enddate><creator>Kitaura, Ryo</creator><creator>Imazu, Naoki</creator><creator>Kobayashi, Keita</creator><creator>Shinohara, Hisanori</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20080201</creationdate><title>Fabrication of Metal Nanowires in Carbon Nanotubes via Versatile Nano-Template Reaction</title><author>Kitaura, Ryo ; Imazu, Naoki ; Kobayashi, Keita ; Shinohara, Hisanori</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a409t-7248f33dc332844e1c95257c9a7591691b0ab750cc420e4faafdb1f451b1c9b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemical synthesis methods</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Crystallization - methods</topic><topic>Exact sciences and technology</topic><topic>Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties</topic><topic>Macromolecular Substances - chemistry</topic><topic>Materials science</topic><topic>Materials Testing</topic><topic>Metals - chemistry</topic><topic>Methods of nanofabrication</topic><topic>Molecular Conformation</topic><topic>Nanocrystalline materials</topic><topic>Nanoscale materials and structures: fabrication and characterization</topic><topic>Nanotechnology - methods</topic><topic>Nanotubes</topic><topic>Nanotubes, Carbon - chemistry</topic><topic>Nanotubes, Carbon - ultrastructure</topic><topic>Particle Size</topic><topic>Physics</topic><topic>Surface Properties</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kitaura, Ryo</creatorcontrib><creatorcontrib>Imazu, Naoki</creatorcontrib><creatorcontrib>Kobayashi, Keita</creatorcontrib><creatorcontrib>Shinohara, Hisanori</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kitaura, Ryo</au><au>Imazu, Naoki</au><au>Kobayashi, Keita</au><au>Shinohara, Hisanori</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of Metal Nanowires in Carbon Nanotubes via Versatile Nano-Template Reaction</atitle><jtitle>Nano letters</jtitle><addtitle>Nano Lett</addtitle><date>2008-02-01</date><risdate>2008</risdate><volume>8</volume><issue>2</issue><spage>693</spage><epage>699</epage><pages>693-699</pages><issn>1530-6984</issn><eissn>1530-6992</eissn><abstract>A nano-template reaction has been developed to fabricate metal nanowires using metallofullerene nanopeapods (i.e., carbon nanotubes (CNTs) encapsulating endohedral metallofullerenes) as starting materials. In this nanometer-scale reaction, the structure of resulting products should possess specific low-dimensional structures, because of their uniform starting orientation of metallofullerene molecules and the rigid restriction of reaction space by the presence of walls of CNTs. Using the nano-template reaction, we have fabricated various Gd nanowires, including a single Gd atomic chain, a one-dimensional alignment of Gd squares, and Gd nanowires that correspond to a one-dimensional segment of the bulk close-packed structure. The same reaction, in principle, can be applied to fabricate more than 20 different types of metal nanowires in the CNTs, which simply are dependent on the use of the corresponding different types of metallofullerenes as encapsulates in the CNTs. The present novel reaction will provide a wide variety of unusual low-dimensional nanowires and nanomaterials in the CNTs, which have not been synthesized via the fabrication techniques that have been reported so far.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>18269254</pmid><doi>10.1021/nl073070d</doi><tpages>7</tpages></addata></record> |
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| subjects | Chemical synthesis methods Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Crystallization - methods Exact sciences and technology Low-dimensional structures (superlattices, quantum well structures, multilayers): structure, and nonelectronic properties Macromolecular Substances - chemistry Materials science Materials Testing Metals - chemistry Methods of nanofabrication Molecular Conformation Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanotechnology - methods Nanotubes Nanotubes, Carbon - chemistry Nanotubes, Carbon - ultrastructure Particle Size Physics Surface Properties Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) |
| title | Fabrication of Metal Nanowires in Carbon Nanotubes via Versatile Nano-Template Reaction |
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