Carbene Chemistry: Stereoregular Polymers from Diazo Compounds

Carbene Chemistry: Stereoregular Polymers from Diazo Compounds

From carbenes to polymers: The synthesis of polymers that bear a polar group (R) on every main‐chain carbon atom, while controlling their stereochemistry, was an elusive goal until quite recently, when it was reported that rhodium(I)‐catalyzed polymerization of functionalized carbenes (from diazo co...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (8), p.1208-1210
1. Verfasser: Noels, Alfred F.
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Sprache:eng
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carbenes
diazo compounds
polymerization
rhodium
stereoregular polymers
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creator Noels, Alfred F.
description From carbenes to polymers: The synthesis of polymers that bear a polar group (R) on every main‐chain carbon atom, while controlling their stereochemistry, was an elusive goal until quite recently, when it was reported that rhodium(I)‐catalyzed polymerization of functionalized carbenes (from diazo compounds) provides access to such stereoregular polymers (see scheme).
doi_str_mv 10.1002/anie.200603660
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subjects carbenes
diazo compounds
polymerization
rhodium
stereoregular polymers
title Carbene Chemistry: Stereoregular Polymers from Diazo Compounds
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