Active peroxo titanium complexes: syntheses, characterization and their potential in the photooxidation of 2-propanol

Active peroxo titanium complexes: syntheses, characterization and their potential in the photooxidation of 2-propanol

Two novel peroxo titanium complexes, Li(2)(NH(4))(4)[Ti(2)(O(2))(2)(cit)(Hcit)](2).5H(2)O and Zn(NH(4))(4)[Ti(4)(O(2))(4)(Hcit)(2)(cit)(2)].12H(2)O (cit = citrate), show encouraging results in the photochemical oxidation of 2-propanol.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-01 (7), p.862-864
Hauptverfasser: Rohe, Markus, Merz, Klaus
Format: Artikel
Sprache:eng
Schlagworte:
2-Propanol - chemistry
2-Propanol - radiation effects
Carbon Dioxide - chemistry
Carbon Dioxide - radiation effects
Lithium - chemistry
Magnetic Resonance Spectroscopy - methods
Models, Molecular
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Oxidation-Reduction
Oxygen - chemistry
Peroxides - chemistry
Photochemistry
Titanium - chemistry
Ultraviolet Rays
Zinc - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Two novel peroxo titanium complexes, Li(2)(NH(4))(4)[Ti(2)(O(2))(2)(cit)(Hcit)](2).5H(2)O and Zn(NH(4))(4)[Ti(4)(O(2))(4)(Hcit)(2)(cit)(2)].12H(2)O (cit = citrate), show encouraging results in the photochemical oxidation of 2-propanol.
ISSN:1359-7345
1364-548X
DOI:10.1039/b716199a