Isolation and Characterization of Carbene Derivatives of La@C82(C s )
The photochemical reaction of La@C82(C s ) with 2-adamantane-2,3-[3H]-diazirine (1) affords the adduct 2 of La@C82(C s ) with adamantylidene (Ad:) in a high selectivity. The two isomers of La@C82(C s )(Ad), 2a and 2b, are isolated by HPLC and characterized by electron spin resonance, mass, and UV−vi...
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| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2008-02, Vol.112 (6), p.1294-1297 |
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| container_title | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
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| creator | Akasaka, Takeshi Kono, Takayoshi Matsunaga, Yoichiro Wakahara, Takatsugu Nakahodo, Tsukasa Ishitsuka, Midori O Maeda, Yutaka Tsuchiya, Takahiro Kato, Tatsuhisa Liu, Michael T. H Mizorogi, Naomi Slanina, Zdenek Nagase, Shigeru |
| description | The photochemical reaction of La@C82(C s ) with 2-adamantane-2,3-[3H]-diazirine (1) affords the adduct 2 of La@C82(C s ) with adamantylidene (Ad:) in a high selectivity. The two isomers of La@C82(C s )(Ad), 2a and 2b, are isolated by HPLC and characterized by electron spin resonance, mass, and UV−vis−near-infrared spectroscopies. The electronic properties of 2a and 2b are very similar to that of the pristine La@C82(C s ), suggesting that 2a and 2b retain the essential electronic and structural character of La@C82(C s ). |
| doi_str_mv | 10.1021/jp7097747 |
| format | Article |
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The electronic properties of 2a and 2b are very similar to that of the pristine La@C82(C s ), suggesting that 2a and 2b retain the essential electronic and structural character of La@C82(C s ).</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>18198854</pmid><doi>10.1021/jp7097747</doi><tpages>4</tpages></addata></record> |
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| title | Isolation and Characterization of Carbene Derivatives of La@C82(C s ) |
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