Total Synthesis of 2-Hydroxytetracosanolide and 2-Hydroxy-24-oxooctacosanolide By Using an Effective Lactonization

We have developed effective methods for the total synthesis of 2‐hydroxytetracosanolide and 2‐hydroxy‐24‐oxooctacosanolide, the defensive salivary secretions of termites. The former natural product isolated from Armitermes neotenicus, a species of termite that inhabits Guyana, contains a 25‐membered...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2008-02, Vol.3 (2), p.462-472
Hauptverfasser:	Shiina, Isamu, Sasaki, Akane, Kikuchi, Takaaki, Fukui, Hiroki
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzoates - chemistry Catalysis Copper - chemistry lactones lactonization macrocycles Macrolides - chemical synthesis Macrolides - chemistry Molecular Structure natural products total synthesis
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