[2+1] Cycloaddition of Nitrene onto C₆₀ Revisited: Interconversion between an Aziridinofullerene and an Azafulleroid

An open and closed case: The reversible interconversion of a [1,2]aziridinofullerene and a [1,6]azafulleroid represents the first such example for a monosubstituted fullerene. While the [1,2]aziridinofullerene rearranges thermally to the [1,6]azafulleroid, the [1,6]azafulleroid rearranges photochemi...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-02, Vol.47 (7), p.1298-1300
Hauptverfasser:	Nakahodo, Tsukasa, Okada, Mitsunori, Morita, Hiroyuki, Yoshimura, Toshiaki, Ishitsuka, Midori O, Tsuchiya, Takahiro, Maeda, Yutaka, Fujihara, Hisashi, Akasaka, Takeshi, Gao, Xingfa, Nagase, Shigeru
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Sprache:	eng
Schlagworte:	azafulleroids fullerenes photochemistry rearrangement structural determination
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creator	Nakahodo, Tsukasa Okada, Mitsunori Morita, Hiroyuki Yoshimura, Toshiaki Ishitsuka, Midori O Tsuchiya, Takahiro Maeda, Yutaka Fujihara, Hisashi Akasaka, Takeshi Gao, Xingfa Nagase, Shigeru
description	An open and closed case: The reversible interconversion of a [1,2]aziridinofullerene and a [1,6]azafulleroid represents the first such example for a monosubstituted fullerene. While the [1,2]aziridinofullerene rearranges thermally to the [1,6]azafulleroid, the [1,6]azafulleroid rearranges photochemically to the [1,2]aziridinofullerene in high yield (see picture).
doi_str_mv	10.1002/anie.200704410
format	Article
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subjects	azafulleroids fullerenes photochemistry rearrangement structural determination
title	[2+1] Cycloaddition of Nitrene onto C₆₀ Revisited: Interconversion between an Aziridinofullerene and an Azafulleroid
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