Steric effects in the dynamics of electrolytes at large applied voltages. II. Modified Poisson-Nernst-Planck equations

In situations involving large potentials or surface charges, the Poisson-Boltzman (PB) equation has shortcomings because it neglects ion-ion interactions and steric effects. This has been widely recognized by the electrochemistry community, leading to the development of various alternative models re...

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Veröffentlicht in:	Physical review. E, Statistical, nonlinear, and soft matter physics Statistical, nonlinear, and soft matter physics, 2007-02, Vol.75 (2 Pt 1), p.021503-021503, Article 021503
Hauptverfasser:	Kilic, Mustafa Sabri, Bazant, Martin Z, Ajdari, Armand
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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