Molecular interactions in alcohol–ethyl methacrylate mixtures
Molecular interaction between alcohols (1-propanol, 1-butanol, s-butanol, t-butanol, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) with ethyl methacrylate has been studied in n-heptane, CCl 4 and benzene at 298 K using FTIR spectroscopic and dielectric methods. The result obtained from both the m...
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| Veröffentlicht in: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2008-02, Vol.69 (2), p.467-470 |
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| container_title | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy |
| container_volume | 69 |
| creator | Dharmalingam, K. Ramachandran, K. Sivagurunathan, P. Kalamse, G.M. |
| description | Molecular interaction between alcohols (1-propanol, 1-butanol,
s-butanol,
t-butanol, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) with ethyl methacrylate has been studied in
n-heptane, CCl
4 and benzene at 298
K using FTIR spectroscopic and dielectric methods. The result obtained from both the methods indicates only the existence of most likely 1:1 complex formation between the alcohol and ethyl methacrylate in these systems. The alkyl chain length of alcohol and the solvent used play a significant role in the strength of hydrogen bond (O
H:O
C) determined on the basis of spectral and dielectric parameters. |
| doi_str_mv | 10.1016/j.saa.2007.04.023 |
| format | Article |
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s-butanol,
t-butanol, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) with ethyl methacrylate has been studied in
n-heptane, CCl
4 and benzene at 298
K using FTIR spectroscopic and dielectric methods. The result obtained from both the methods indicates only the existence of most likely 1:1 complex formation between the alcohol and ethyl methacrylate in these systems. The alkyl chain length of alcohol and the solvent used play a significant role in the strength of hydrogen bond (O
H:O
C) determined on the basis of spectral and dielectric parameters.</description><identifier>ISSN: 1386-1425</identifier><identifier>DOI: 10.1016/j.saa.2007.04.023</identifier><identifier>PMID: 17540616</identifier><language>eng</language><publisher>England: Elsevier B.V</publisher><subject>Acrylic esters ; Alcohols ; Alcohols - chemistry ; Dielectric relaxation ; FTIR spectroscopy ; Hydrogen bonding ; Methacrylates - chemistry ; Solvent effects ; Spectroscopy, Fourier Transform Infrared</subject><ispartof>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2008-02, Vol.69 (2), p.467-470</ispartof><rights>2007 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c351t-ee361df11f1b8c5e6d5a7ddef37f8dba202e8f650e3a295273c0257c724f33ae3</citedby><cites>FETCH-LOGICAL-c351t-ee361df11f1b8c5e6d5a7ddef37f8dba202e8f650e3a295273c0257c724f33ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.saa.2007.04.023$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17540616$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dharmalingam, K.</creatorcontrib><creatorcontrib>Ramachandran, K.</creatorcontrib><creatorcontrib>Sivagurunathan, P.</creatorcontrib><creatorcontrib>Kalamse, G.M.</creatorcontrib><title>Molecular interactions in alcohol–ethyl methacrylate mixtures</title><title>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</title><addtitle>Spectrochim Acta A Mol Biomol Spectrosc</addtitle><description>Molecular interaction between alcohols (1-propanol, 1-butanol,
s-butanol,
t-butanol, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) with ethyl methacrylate has been studied in
n-heptane, CCl
4 and benzene at 298
K using FTIR spectroscopic and dielectric methods. The result obtained from both the methods indicates only the existence of most likely 1:1 complex formation between the alcohol and ethyl methacrylate in these systems. The alkyl chain length of alcohol and the solvent used play a significant role in the strength of hydrogen bond (O
H:O
C) determined on the basis of spectral and dielectric parameters.</description><subject>Acrylic esters</subject><subject>Alcohols</subject><subject>Alcohols - chemistry</subject><subject>Dielectric relaxation</subject><subject>FTIR spectroscopy</subject><subject>Hydrogen bonding</subject><subject>Methacrylates - chemistry</subject><subject>Solvent effects</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><issn>1386-1425</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kL1OwzAUhT2AaCk8AAvKxJZwbcd2KgaEEH9SEQvMlmvfqK6cptgJohvvwBvyJKRqJTamoyt950j3I-SMQkGBystlkYwpGIAqoCyA8QMyprySOS2ZGJHjlJYAQCsGR2RElShBUjkm189tQNsHEzO_6jAa2_l2lYYjM8G2izb8fH1jt9iErBnC2LgJpsOs8Z9dHzGdkMPahISn-5yQt_u719vHfPby8HR7M8stF7TLEbmkrqa0pvPKCpROGOUc1lzVlZsbBgyrWgpAbthUMMUtMKGsYmXNuUE-IRe73XVs33tMnW58shiCWWHbJ62ASajK6QDSHWhjm1LEWq-jb0zcaAp6a0ov9WBKb01pKPVgauic78f7eYPur7HXNABXOwCHFz88Rp2sx5VF5yPaTrvW_zP_C4IxfSM</recordid><startdate>20080201</startdate><enddate>20080201</enddate><creator>Dharmalingam, K.</creator><creator>Ramachandran, K.</creator><creator>Sivagurunathan, P.</creator><creator>Kalamse, G.M.</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20080201</creationdate><title>Molecular interactions in alcohol–ethyl methacrylate mixtures</title><author>Dharmalingam, K. ; Ramachandran, K. ; Sivagurunathan, P. ; Kalamse, G.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c351t-ee361df11f1b8c5e6d5a7ddef37f8dba202e8f650e3a295273c0257c724f33ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Acrylic esters</topic><topic>Alcohols</topic><topic>Alcohols - chemistry</topic><topic>Dielectric relaxation</topic><topic>FTIR spectroscopy</topic><topic>Hydrogen bonding</topic><topic>Methacrylates - chemistry</topic><topic>Solvent effects</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dharmalingam, K.</creatorcontrib><creatorcontrib>Ramachandran, K.</creatorcontrib><creatorcontrib>Sivagurunathan, P.</creatorcontrib><creatorcontrib>Kalamse, G.M.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dharmalingam, K.</au><au>Ramachandran, K.</au><au>Sivagurunathan, P.</au><au>Kalamse, G.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular interactions in alcohol–ethyl methacrylate mixtures</atitle><jtitle>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</jtitle><addtitle>Spectrochim Acta A Mol Biomol Spectrosc</addtitle><date>2008-02-01</date><risdate>2008</risdate><volume>69</volume><issue>2</issue><spage>467</spage><epage>470</epage><pages>467-470</pages><issn>1386-1425</issn><abstract>Molecular interaction between alcohols (1-propanol, 1-butanol,
s-butanol,
t-butanol, 1-pentanol, 1-heptanol, 1-octanol and 1-decanol) with ethyl methacrylate has been studied in
n-heptane, CCl
4 and benzene at 298
K using FTIR spectroscopic and dielectric methods. The result obtained from both the methods indicates only the existence of most likely 1:1 complex formation between the alcohol and ethyl methacrylate in these systems. The alkyl chain length of alcohol and the solvent used play a significant role in the strength of hydrogen bond (O
H:O
C) determined on the basis of spectral and dielectric parameters.</abstract><cop>England</cop><pub>Elsevier B.V</pub><pmid>17540616</pmid><doi>10.1016/j.saa.2007.04.023</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 1386-1425 |
| ispartof | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2008-02, Vol.69 (2), p.467-470 |
| issn | 1386-1425 |
| language | eng |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Acrylic esters Alcohols Alcohols - chemistry Dielectric relaxation FTIR spectroscopy Hydrogen bonding Methacrylates - chemistry Solvent effects Spectroscopy, Fourier Transform Infrared |
| title | Molecular interactions in alcohol–ethyl methacrylate mixtures |
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