Separation of Olefin/Paraffin Mixtures Using Zwitterionic Silver Complexes as Transport Carriers
Zwitterionic silver nitrate salts of 1‐(1‐methyl‐3‐imidazolio)propane‐3‐sulfonate, 1‐(1‐methyl‐1‐pyrrolidinio)propane‐3‐sulfonate, and 1‐(4‐methyl‐4‐morpholio)propane‐3‐sulfonate have been prepared and tested as carriers for facilitated olefin transport membranes in the separation of ethylene/ethane...
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| Veröffentlicht in: | Chemistry : a European journal 2007-03, Vol.13 (9), p.2655-2660 |
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| container_end_page | 2660 |
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| container_issue | 9 |
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| container_title | Chemistry : a European journal |
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| creator | Kim, Hoon Sik Bae, Jin Yong Park, Sang Joon Lee, Hyunjoo Bae, Hyun Woo Kang, Sang Ook Lee, Sang Deuk Choi, Dai Ki |
| description | Zwitterionic silver nitrate salts of 1‐(1‐methyl‐3‐imidazolio)propane‐3‐sulfonate, 1‐(1‐methyl‐1‐pyrrolidinio)propane‐3‐sulfonate, and 1‐(4‐methyl‐4‐morpholio)propane‐3‐sulfonate have been prepared and tested as carriers for facilitated olefin transport membranes in the separation of ethylene/ethane, propylene/propane, and C4 mixtures. The interactions of olefins with silver ions bound to sulfonate groups were investigated by FTIR spectroscopy as well as the correlation between the binding affinity of olefins and facilitated transport.
Various imidazolium‐, pyrrolidinium‐ and morpholinium‐based zwitterionic silver complexes have been prepared and their performances as carriers for facilitated transport composite membranes investigated for selective separation of ethylene/ethane, propylene/propane, and C4 mixtures (see picture). |
| doi_str_mv | 10.1002/chem.200600869 |
| format | Article |
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Various imidazolium‐, pyrrolidinium‐ and morpholinium‐based zwitterionic silver complexes have been prepared and their performances as carriers for facilitated transport composite membranes investigated for selective separation of ethylene/ethane, propylene/propane, and C4 mixtures (see picture).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.200600869</identifier><identifier>PMID: 17171729</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>ionic liquids ; ionomer ; membranes ; olefins ; zwitterions</subject><ispartof>Chemistry : a European journal, 2007-03, Vol.13 (9), p.2655-2660</ispartof><rights>Copyright © 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2969-b589ad2fd6c4151f16e2f29e312b1dfb38eb0bd09c1f21960ac4615f4ae3dd803</citedby><cites>FETCH-LOGICAL-c2969-b589ad2fd6c4151f16e2f29e312b1dfb38eb0bd09c1f21960ac4615f4ae3dd803</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.200600869$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.200600869$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17171729$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Hoon Sik</creatorcontrib><creatorcontrib>Bae, Jin Yong</creatorcontrib><creatorcontrib>Park, Sang Joon</creatorcontrib><creatorcontrib>Lee, Hyunjoo</creatorcontrib><creatorcontrib>Bae, Hyun Woo</creatorcontrib><creatorcontrib>Kang, Sang Ook</creatorcontrib><creatorcontrib>Lee, Sang Deuk</creatorcontrib><creatorcontrib>Choi, Dai Ki</creatorcontrib><title>Separation of Olefin/Paraffin Mixtures Using Zwitterionic Silver Complexes as Transport Carriers</title><title>Chemistry : a European journal</title><addtitle>Chemistry - A European Journal</addtitle><description>Zwitterionic silver nitrate salts of 1‐(1‐methyl‐3‐imidazolio)propane‐3‐sulfonate, 1‐(1‐methyl‐1‐pyrrolidinio)propane‐3‐sulfonate, and 1‐(4‐methyl‐4‐morpholio)propane‐3‐sulfonate have been prepared and tested as carriers for facilitated olefin transport membranes in the separation of ethylene/ethane, propylene/propane, and C4 mixtures. The interactions of olefins with silver ions bound to sulfonate groups were investigated by FTIR spectroscopy as well as the correlation between the binding affinity of olefins and facilitated transport.
Various imidazolium‐, pyrrolidinium‐ and morpholinium‐based zwitterionic silver complexes have been prepared and their performances as carriers for facilitated transport composite membranes investigated for selective separation of ethylene/ethane, propylene/propane, and C4 mixtures (see picture).</description><subject>ionic liquids</subject><subject>ionomer</subject><subject>membranes</subject><subject>olefins</subject><subject>zwitterions</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFkD1v2zAQhomiQeMmXTMGnLrJOZISZY6tYDsB8uEgMQxkYSnp2LLVV0i5dv59ZNhIuwU33OHwvM_wEnLGYMwA-EXxC-sxB5AAE6k-kBFLOItEKpOPZAQqTiOZCHVMPofwGwCUFOITOWbpbrgakR8P2Blvetc2tLX0rkLrmovF8LLDQW_ctl97DHQZXPOTPm1c36MfYFfQB1f9RU-ztu4q3A6MCfTRmyZ0re9pZrx36MMpObKmCvjlsE_IcjZ9zC6j67v5VfbtOiq4kirKk4kyJbelLGKWMMskcssVCsZzVtpcTDCHvARVMMuZkmCKWLLExgZFWU5AnJCve2_n2-c1hl7XLhRYVabBdh10CjyJVSoHcLwHC9-G4NHqzrva-BfNQO861btO9VunQ-D8YF7nNZb_8EOJA6D2wMZV-PKOTmeX05v_5dE-60KP27es8X-0TEWa6NXtXC_E_WK--j7XM_EKxz6UQQ</recordid><startdate>20070316</startdate><enddate>20070316</enddate><creator>Kim, Hoon Sik</creator><creator>Bae, Jin Yong</creator><creator>Park, Sang Joon</creator><creator>Lee, Hyunjoo</creator><creator>Bae, Hyun Woo</creator><creator>Kang, Sang Ook</creator><creator>Lee, Sang Deuk</creator><creator>Choi, Dai Ki</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070316</creationdate><title>Separation of Olefin/Paraffin Mixtures Using Zwitterionic Silver Complexes as Transport Carriers</title><author>Kim, Hoon Sik ; Bae, Jin Yong ; Park, Sang Joon ; Lee, Hyunjoo ; Bae, Hyun Woo ; Kang, Sang Ook ; Lee, Sang Deuk ; Choi, Dai Ki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2969-b589ad2fd6c4151f16e2f29e312b1dfb38eb0bd09c1f21960ac4615f4ae3dd803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>ionic liquids</topic><topic>ionomer</topic><topic>membranes</topic><topic>olefins</topic><topic>zwitterions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Hoon Sik</creatorcontrib><creatorcontrib>Bae, Jin Yong</creatorcontrib><creatorcontrib>Park, Sang Joon</creatorcontrib><creatorcontrib>Lee, Hyunjoo</creatorcontrib><creatorcontrib>Bae, Hyun Woo</creatorcontrib><creatorcontrib>Kang, Sang Ook</creatorcontrib><creatorcontrib>Lee, Sang Deuk</creatorcontrib><creatorcontrib>Choi, Dai Ki</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Hoon Sik</au><au>Bae, Jin Yong</au><au>Park, Sang Joon</au><au>Lee, Hyunjoo</au><au>Bae, Hyun Woo</au><au>Kang, Sang Ook</au><au>Lee, Sang Deuk</au><au>Choi, Dai Ki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Separation of Olefin/Paraffin Mixtures Using Zwitterionic Silver Complexes as Transport Carriers</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry - A European Journal</addtitle><date>2007-03-16</date><risdate>2007</risdate><volume>13</volume><issue>9</issue><spage>2655</spage><epage>2660</epage><pages>2655-2660</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Zwitterionic silver nitrate salts of 1‐(1‐methyl‐3‐imidazolio)propane‐3‐sulfonate, 1‐(1‐methyl‐1‐pyrrolidinio)propane‐3‐sulfonate, and 1‐(4‐methyl‐4‐morpholio)propane‐3‐sulfonate have been prepared and tested as carriers for facilitated olefin transport membranes in the separation of ethylene/ethane, propylene/propane, and C4 mixtures. The interactions of olefins with silver ions bound to sulfonate groups were investigated by FTIR spectroscopy as well as the correlation between the binding affinity of olefins and facilitated transport.
Various imidazolium‐, pyrrolidinium‐ and morpholinium‐based zwitterionic silver complexes have been prepared and their performances as carriers for facilitated transport composite membranes investigated for selective separation of ethylene/ethane, propylene/propane, and C4 mixtures (see picture).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>17171729</pmid><doi>10.1002/chem.200600869</doi><tpages>6</tpages></addata></record> |
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| subjects | ionic liquids ionomer membranes olefins zwitterions |
| title | Separation of Olefin/Paraffin Mixtures Using Zwitterionic Silver Complexes as Transport Carriers |
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