Supermolecular Building Blocks (SBBs) and Crystal Design:  12-Connected Open Frameworks Based on a Molecular Cubohemioctahedron

The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid tetracarboxylato ligands in such a manner that 12-connected fcu nets with nanoscale features are generated. 3,5-H4ATC, L1, faci...

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Veröffentlicht in:	Journal of the American Chemical Society 2008-02, Vol.130 (5), p.1560-1561
Hauptverfasser:	Cairns, Amy J, Perman, Jason A, Wojtas, Lukasz, Kravtsov, Victor Ch, Alkordi, Mohamed H, Eddaoudi, Mohamed, Zaworotko, Michael J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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