Cyclic [5]Paraphenyleneacetylene: Synthesis, Properties, and Formation of a Ring-in-Ring Complex Showing a Considerably Large Association Constant and Entropy Effect

In the ring: The title compound ([5]CPPA), the smallest belt‐shaped conjugated system known to date, forms a considerably stable ring‐in‐ring complex with [8]CPPA (see picture). [8]CPPA⊃[5]CPPA has a smaller contact area than [9]CPPA⊃[6]CPPA but its large Ka and ΔH values reveal that the interaction...

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Veröffentlicht in:	Angewandte Chemie International Edition 2007-01, Vol.46 (7), p.1086-1088
Hauptverfasser:	Kawase, Takeshi, Nishiyama, Yoshitaka, Nakamura, Takamitsu, Ebi, Takahiro, Matsumoto, Kouzou, Kurata, Hiroyuki, Oda, Masaji
Format:	Artikel
Sprache:	eng
Schlagworte:	cyclic alkynes host-guest systems inclusion compounds noncovalent interactions strained molecules
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creator	Kawase, Takeshi Nishiyama, Yoshitaka Nakamura, Takamitsu Ebi, Takahiro Matsumoto, Kouzou Kurata, Hiroyuki Oda, Masaji
description	In the ring: The title compound ([5]CPPA), the smallest belt‐shaped conjugated system known to date, forms a considerably stable ring‐in‐ring complex with [8]CPPA (see picture). [8]CPPA⊃[5]CPPA has a smaller contact area than [9]CPPA⊃[6]CPPA but its large Ka and ΔH values reveal that the interaction results from the electrostatic attractive force rather than the dispersion force.
doi_str_mv	10.1002/anie.200603707
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source	Wiley Online Library Journals Frontfile Complete
subjects	cyclic alkynes host-guest systems inclusion compounds noncovalent interactions strained molecules
title	Cyclic [5]Paraphenyleneacetylene: Synthesis, Properties, and Formation of a Ring-in-Ring Complex Showing a Considerably Large Association Constant and Entropy Effect
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