Olefin Epoxidation by Alkyl Hydroperoxide with a Novel Cross-Bridged Cyclam Manganese Complex:  Demonstration of Oxygenation by Two Distinct Reactive Intermediates

Olefin epoxidation provides an operative protocol to investigate the oxygen transfer process in nature. A novel manganese complex with a cross-bridged cyclam ligand, MnIV(Me2EBC)(OH)2 2+ (Me2EBC = 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane), was used to study the epoxidation mechanism w...

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Veröffentlicht in:	Inorganic chemistry 2007-03, Vol.46 (6), p.2173-2180
Hauptverfasser:	Yin, Guochuan, Danby, Andrew M, Kitko, David, Carter, John D, Scheper, William M, Busch, Daryle H
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Catalysis Epoxy Compounds - chemistry Hydrogen Peroxide - chemistry Manganese - chemistry Models, Molecular Oxygen - chemistry Spectrometry, Mass, Electrospray Ionization
Online-Zugang:	Volltext
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