Dipyrrolyl-Functionalized Bipyridine-Based Anion Receptors for Emission-Based Selective Detection of Dihydrogen Phosphate

New cationic anion receptors, based on the use of pyrrole‐substituted bipyridine and coordinated to transition metals, are described. Specifically, polypyridine–ruthenium and –rhodium cores have been functionalized to generate an anion binding site. The design was chosen to probe the influence of th...

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Veröffentlicht in:	Chemistry : a European journal 2007-01, Vol.13 (5), p.1374-1381
Hauptverfasser:	Plitt, Patrick, Gross, Dustin E., Lynch, Vincent M., Sessler, Jonathan L.
Format:	Artikel
Sprache:	eng
Schlagworte:	2,2'-Dipyridyl - chemistry anion receptors Anions - chemistry Binding Sites Chlorides - chemistry Dimethyl Sulfoxide - chemistry hydrogen bonds molecular recognition Molecular Structure Phosphates - analysis Phosphates - chemistry pyrroles Pyrroles - chemistry Rhodium - chemistry Ruthenium - chemistry sensors Spectrum Analysis Titrimetry Transition Elements - chemistry X-Ray Diffraction
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