Synthesis, Characterization, and Reactivity of a d2, Mo(IV) Complex Supported by a New OCO−Trianionic Pincer Ligand

The new terphenyl pincer precursor 3,3‘ ‘-di-tert-butyl-1,1‘:3‘,1‘ ‘-terphenyl-2,2‘ ‘-diol (1) is examined for its ability to support early transition metals as a trianionic ligand. Metalation proceeds smoothly at −35 °C with Mo(NMe2)4 to provide the Mo(IV), d2 amido−amine complex [3,3‘ ‘-di-tert-bu...

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Veröffentlicht in:	Journal of the American Chemical Society 2008-01, Vol.130 (4), p.1116-1117
Hauptverfasser:	Sarkar, Soumya, Carlson, Adam R, Veige, Melanie K, Falkowski, Joseph M, Abboud, Khalil A, Veige, Adam S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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