Low-Temperature Spectral Observation of the First Six-Coordinate Nitrosyl Complexes of Cobalt(II) meso-Tetratolylporphyrin with Trans Nitrogen Base Ligands

Low-temperature interaction of nitrogen base ligands with layered Co(TTP)(NO) (TTP = meso-tetratolylporphyrinato dianion) as well as its toluene solution leads to the formation of the first six-coordinate species of the general formula (B)Co(TTP)(NO) (where B = piperidine and pyridine). The ν(NO) st...

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Veröffentlicht in:	Inorganic chemistry 2007-03, Vol.46 (5), p.1526-1528
Hauptverfasser:	Kurtikyan, Tigran S, Markaryan, Emil R, Mardyukov, Artur N, Goodwin, John A
Format:	Artikel
Sprache:	eng
Schlagworte:	Cobalt - chemistry Ligands Nitrogen - chemistry Nitroso Compounds - chemistry Organometallic Compounds - chemistry Porphyrins - chemistry Sensitivity and Specificity Spectroscopy, Fourier Transform Infrared - methods Temperature
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