Alkali-Metal-Induced Enhancement of Hydrogen Adsorption in C60 Fullerene: An ab Initio Study
It is demonstrated that the doping of alkali metal atoms on fullerene, C60, remarkably enhances the molecular hydrogen adsorption capacity of fullerenes, which is higher than that of conventionally known other fullerene complexes. This effect is observed to be more pronounced for sodium than lithium...
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| Veröffentlicht in: | Nano letters 2008-01, Vol.8 (1), p.13-19 |
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| creator | Chandrakumar, K. R. S Ghosh, Swapan K |
| description | It is demonstrated that the doping of alkali metal atoms on fullerene, C60, remarkably enhances the molecular hydrogen adsorption capacity of fullerenes, which is higher than that of conventionally known other fullerene complexes. This effect is observed to be more pronounced for sodium than lithium atom. The formation of stable complex forms of a sodium-doped fullerene molecule, Na8C60, and the corresponding hydrogenated species, [Na(H2)6]8C60, with 48 hydrogen molecules has been demonstrated to lead to a hydrogen adsorption density of ∼9.5 wt %. One of the main factors favoring the interactions involved is attributed to the pronounced charge transfer from the sodium atom to the C60 molecule and electrostatic interaction between the ion and the dihydrogen. The suitability of these complexes for developing fullerene-based hydrogen storage materials is discussed. |
| doi_str_mv | 10.1021/nl071456i |
| format | Article |
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R. S ; Ghosh, Swapan K</creator><creatorcontrib>Chandrakumar, K. R. S ; Ghosh, Swapan K</creatorcontrib><description>It is demonstrated that the doping of alkali metal atoms on fullerene, C60, remarkably enhances the molecular hydrogen adsorption capacity of fullerenes, which is higher than that of conventionally known other fullerene complexes. This effect is observed to be more pronounced for sodium than lithium atom. The formation of stable complex forms of a sodium-doped fullerene molecule, Na8C60, and the corresponding hydrogenated species, [Na(H2)6]8C60, with 48 hydrogen molecules has been demonstrated to lead to a hydrogen adsorption density of ∼9.5 wt %. One of the main factors favoring the interactions involved is attributed to the pronounced charge transfer from the sodium atom to the C60 molecule and electrostatic interaction between the ion and the dihydrogen. 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One of the main factors favoring the interactions involved is attributed to the pronounced charge transfer from the sodium atom to the C60 molecule and electrostatic interaction between the ion and the dihydrogen. The suitability of these complexes for developing fullerene-based hydrogen storage materials is discussed.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>Materials science</subject><subject>Physics</subject><subject>Solid surfaces and solid-solid interfaces</subject><subject>Specific materials</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNpF0b1OwzAQB3ALgWgpDLwA8gJb4JwPf7BFVUsrFTEAs-XYDqQ4TomToRsrr8mTEEQp093w0-nufwidE7gmEJMb74CRNKPVARqTLIGIChEf7nuejtBJCGsAEEkGx2hEOPCMAxsjmbs35aro3nbKRUtvem0NnvlX5bWtre9wU-LF1rTNi_U4N6FpN13VeFx5PKWA571ztrXe3n59fOLcY1Xgpa8Ggh-73mxP0VGpXLBnuzpBz_PZ03QRrR7ultN8Fak4gy7iJuGFSEmcEkoNqBTKlFuqdGI040WRMKq1zoAnrIgJ46ogjAnG4mFbIIIkE3T1O3fTNu-9DZ2sq6Ctc8rbpg-SDYpCHA_wYgf7orZGbtqqVu1W_kUygMsdUEErV7ZDElX4d0KINEvpv1M6yHXTt364TxKQPy-R-5ck3_QCefU</recordid><startdate>200801</startdate><enddate>200801</enddate><creator>Chandrakumar, K. 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| source | American Chemical Society Journals |
| subjects | Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Fullerenes and related materials diamonds, graphite Materials science Physics Solid surfaces and solid-solid interfaces Specific materials Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) |
| title | Alkali-Metal-Induced Enhancement of Hydrogen Adsorption in C60 Fullerene: An ab Initio Study |
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