Emission of Tris(2,2‘-bipyridine)ruthenium(II) by Coreactant Electrogenerated Chemiluminescence:  From O2-Insensitive to Highly O2-Sensitive

We describe the influence of dissolved oxygen on the emission of Ru(bpy)3 2+ (bpy = 2,2‘-bipyridine) by electrogenerated chemiluminescence (ECL) with tertiary amine as coreactant in aqueous solutions. The significance of the reactions between molecular oxygen and the ECL intermediate reducing radica...

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Veröffentlicht in:The journal of physical chemistry. B 2005-06, Vol.109 (24), p.12049-12053
Hauptverfasser: Zheng, Huzhi, Zu, Yanbing
Format: Artikel
Sprache:eng
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