Stability and Reactivity of All-Metal Aromatic and Antiaromatic Systems in Light of the Principles of Maximum Hardness and Minimum Polarizability

It is demonstrated that among various possible isomers of all-metal aromatic compounds such as Al4 2- and their complexes the most stable isomer with the minimum energy is the hardest and the least polarizable. A similar situation is observed for different isomers of all-metal antiaromatic compounds...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2005-10, Vol.109 (42), p.9590-9597
Hauptverfasser:	Chattaraj, P. K, Roy, D. R, Elango, M, Subramanian, V
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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