Gas Phase Structure of Ruppert's Reagent, CF3SiMe3

CF3SiMe3 (Ruppert's reagent) has been investigated by gas phase electron diffraction, microwave spectroscopy and quantum chemical methods, deriving structural parameters and the barrier height for the methyl torsion. The bond length of the Si−CF3 bond, 1.941(3) Å, is the longest Si−C bond obser...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2005-09, Vol.109 (37), p.8438-8442
Hauptverfasser:	Klatte, Katrin, Christen, Dines, Merke, Ilona, Stahl, Wolfgang, Oberhammer, Heinz
Format:	Artikel
Sprache:	eng
Schlagworte:	Fluorine - chemistry Gases Hydrocarbons, Fluorinated - chemistry Indicators and Reagents - chemistry Microwaves Models, Molecular Molecular Conformation Quantum Theory Silicon - chemistry Spectrum Analysis Trimethylsilyl Compounds - chemistry
Online-Zugang:	Volltext
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