Electronic Structure and Band Gaps in Cationic Heterocyclic Oligomers. Multidimensional Analysis of the Interplay of Heteroatoms, Substituents, Molecular Length, and Charge on Redox and Transparency Characteristics

Oxidative doping of extended π-conjugated polymers and oligomers produces dramatic changes in optical and electrical properties, arising from polaron and soliton-derived midgap states. Despite the great importance of such changes for materials properties, far less is known about the cationic polaron...

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Veröffentlicht in:	The journal of physical chemistry. B 2005-03, Vol.109 (8), p.3126-3138
Hauptverfasser:	Hutchison, Geoffrey R., Ratner, Mark A., Marks, Tobin J.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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