An Experimental and Theoretical Evaluation of the Reactions of Silver Hyponitrite with Phosphorus Halides. In Search of the Elusive Phosphorus-Containing Hyponitrites

In the reaction of F2PBr, F2P(O)Br, (C6F5)2PBr, (CH3)2P(S)Br, and (CH3)2P(O)Cl with silver hyponitrite (AgONNOAg), nitrous oxide (N2O) and μ-oxo phosphorus species were obtained in all cases rather than the plausible hyponitrite alternative. Theoretical calculations of the geometries and expected d...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2005-02, Vol.109 (7), p.1420-1429
Hauptverfasser:	Joo, Hyun, Salam Biswas, M. A, Hill, William E, McKee, Michael L
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Computer Simulation Halogens - chemistry Models, Chemical Nitrites - chemistry Organophosphorus Compounds - chemistry Phosphorus Compounds - chemistry Silver - chemistry Thermodynamics
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