Kinetics and Mechanism of (CF3)2CHOCH3 Reaction with OH Radicals in an Environmental Reaction Chamber

The atmospheric chemistry of (CF3)2CHOCH3, a possible HCFC/HFC alternative, was studied using a smog chamber/FT-IR technique. OH radicals were prepared by the photolysis of ozone in a 200-Torr H2O/O3/O2 gas mixture held in an 11.5-dm3 temperature-controlled chamber. The rate constant, k 1, for the r...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2005-06, Vol.109 (21), p.4766-4771
Hauptverfasser:	Chen, L, Kutsuna, S, Tokuhashi, K, Sekiya, A, Tamai, R, Hibino, Y
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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