2,6,7-Trithiabicyclo[2.2.2]octanes as Promising Photolabile Tags for Combinatorial Encoding

The adducts of trithiabicyclo[2.2.2]octane (TTBO) and carbonyl compounds undergo efficient photoinduced fragmentation with quantum yields comparable to that of dithiane adducts. The effect of the third sulfur on the stability of the respective radical cations and radicals is examined computationally...

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Veröffentlicht in:	Journal of organic chemistry 2008-01, Vol.73 (1), p.335-338
Hauptverfasser:	Valiulin, Roman A, Kutateladze, Andrei G
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Free radicals chemistry Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Organic chemistry Preparations and properties Reactivity and mechanisms
Online-Zugang:	Volltext
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