Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range of different nucleophiles or SN2'-type allylic substitution, leads to the formation of C---H, ---C, ---O, ---N, ---S, and other bonds with very high levels of asymmet...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-01, Vol.47 (2), p.258-297
Hauptverfasser: Lu, Zhan, Ma, Shengming
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Sprache:eng
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allylation
asymmetric catalysis
chiral ligands
natural products
regioselectivity
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Ma, Shengming
description Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range of different nucleophiles or SN2'-type allylic substitution, leads to the formation of C---H, ---C, ---O, ---N, ---S, and other bonds with very high levels of asymmetric induction. The reaction may tolerate a broad range of functional groups and has been applied successfully to the synthesis of many natural products and new chiral compounds.
doi_str_mv 10.1002/anie.200605113
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subjects allylation
asymmetric catalysis
chiral ligands
natural products
regioselectivity
title Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis
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