Axially Chiral β,β′-Bisporphyrins: Synthesis and Configurational Stability Tuned by the Central Metals

In this paper, the synthesis of a new type of intrinsically chiral, directly β,β′-linked, octa-meso-aryl-substituted bisporphyrins is described, by using an optimized Suzuki−Miyaura coupling procedure. This strategy leads to a broad variety of such axially chiral ‘superbiaryls’, differing in their m...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2008-12, Vol.130 (52), p.17812-17825
Hauptverfasser:	Bringmann, Gerhard, Götz, Daniel C. G, Gulder, Tobias A. M, Gehrke, Tim H, Bruhn, Torsten, Kupfer, Thomas, Radacki, Krzysztof, Braunschweig, Holger, Heckmann, Alexander, Lambert, Christoph
Format:	Artikel
Sprache:	eng
Schlagworte:	Boronic Acids - chemistry Crystallography, X-Ray Electrochemistry Esters - chemistry Metalloporphyrins - chemical synthesis Metalloporphyrins - chemistry Models, Molecular Molecular Conformation Porphyrins - chemical synthesis Porphyrins - chemistry Spectrophotometry, Ultraviolet Stereoisomerism Thermodynamics
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!