Comparison of Chiral and Racemic Forms of Zinc Cyclohexane trans-1,2-Dicarboxylate Frameworks: A Structural, Computational, and Calorimetric Study

An integrated study of the organic–inorganic framework material zinc cyclohexane trans‐1,2‐dicarboxylate involving synthesis, structure elucidation, computer simulation, and calorimetry shows that the chiral R,R form (right in picture) is less stable than its racemic R,R/S,S analogue (left) and adop...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-10, Vol.47 (45), p.8634-8637
Hauptverfasser:	Bailey, Andrew J, Lee, Clare, Feller, Russell K, Orton, James B, Mellot-Draznieks, Caroline, Slater, Ben, Harrison, William T.A, Simoncic, P, Navrotsky, A, Grossel, Martin C, Cheetham, Anthony K
Format:	Artikel
Sprache:	eng
Schlagworte:	Calorimetry chirality Computer Simulation crystal engineering Crystallography, X-Ray Cyclohexanecarboxylic Acids - chemistry Dicarboxylic Acids - chemistry Models, Chemical Models, Molecular Molecular Conformation molecular modeling organic-inorganic hybrid composites Stereoisomerism
Online-Zugang:	Volltext
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