Ethylene/Polar Monomer Copolymerization Behavior of Bis(phenoxy–imine)Ti Complexes: Formation of Polar Monomer Copolymers

Ethylene/Polar Monomer Copolymerization Behavior of Bis(phenoxy–imine)Ti Complexes: Formation of Polar Monomer Copolymers

Bis(phenoxy−imine) Ti complexes bearing a phenyl group ortho to the phenoxy-O can mediate the copolymerization of ethylene and 5-hexene-1-yl-acetate though they are group 4 transition metal catalysts.

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Veröffentlicht in:Journal of the American Chemical Society 2008-12, Vol.130 (52), p.17636-17637
Hauptverfasser: Terao, Hiroshi, Ishii, Seiichi, Mitani, Makoto, Tanaka, Hidetsugu, Fujita, Terunori
Format: Artikel
Sprache:eng
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Zusammenfassung:Bis(phenoxy−imine) Ti complexes bearing a phenyl group ortho to the phenoxy-O can mediate the copolymerization of ethylene and 5-hexene-1-yl-acetate though they are group 4 transition metal catalysts.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja8060479