Biomimetic Carbene-Catalyzed Oxidations of Aldehydes Using TEMPO

Transition‐metal‐free organocatalytic oxidations of various aldehydes proceed with the TEMPO radical as a mild organic oxidant; the resulting TEMPO esters are formed in moderate to excellent yields (see scheme). N‐Heterocyclic carbenes (NHCs) are efficient catalysts and activate aldehydes for electr...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-10, Vol.47 (45), p.8727-8730
Hauptverfasser:	Guin, Joyram, De Sarkar, Suman, Grimme, Stefan, Studer, Armido
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Biomimetics carbenes Catalysis Cyclic N-Oxides - chemistry density functional calculations Esters - chemical synthesis Esters - chemistry Heterocyclic Compounds - chemistry Methane - analogs & derivatives Methane - chemistry Molecular Structure organocatalysis Oxidation-Reduction oxidations Stereoisomerism synthetic methods
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