Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

The dithiolate cofactor for the [FeFe]-hydrogenase models, Fe2(xdt)(CO)2(dppv)2 (where xdt = 1,3-propanedithiolate (pdt), azadithiolate (adt), (SCH2)2NH, and oxadithiolate (odt), (SCH2)2O; dppv = cis-1,2-bis(diphenylphosphino)ethylene) have been probed for their functionality as proton relays enabli...

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Veröffentlicht in:	Journal of the American Chemical Society 2008-12, Vol.130 (50), p.16834-16835
Hauptverfasser:	Barton, Bryan E, Olsen, Matthew T, Rauchfuss, Thomas B
Format:	Artikel
Sprache:	eng
Schlagworte:	Aza Compounds - chemistry Calcitriol - analogs & derivatives Calcitriol - chemistry Catalytic Domain Hydrogenase - chemistry Hydrogenase - metabolism Iron-Sulfur Proteins - chemistry Iron-Sulfur Proteins - metabolism Models, Biological Molecular Structure Protons Sulfhydryl Compounds - chemistry
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