Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surfaces for One-Pot C----C Bond Forming Reactions

Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surfaces for One-Pot C----C Bond Forming Reactions

D'you know what amine? Primary and tertiary amines are both immobilized on the same silica–alumina surface by silane‐coupling reactions. The resultant silica–alumina‐supported double‐amines are found to exhibit excellent catalysis for 1,3‐dinitroalkane synthesis from various aldehydes with nitr...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-01, Vol.47 (48), p.9230-9235
Hauptverfasser: Motokura, Ken, Tada, Mizuki, Iwasawa, Yasuhiro
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Sprache:eng
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cooperative effects
CC coupling
immobilization
nitroalkanes
supported catalysts
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container_issue 48
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container_title Angewandte Chemie (International ed.)
container_volume 47
creator Motokura, Ken
Tada, Mizuki
Iwasawa, Yasuhiro
description D'you know what amine? Primary and tertiary amines are both immobilized on the same silica–alumina surface by silane‐coupling reactions. The resultant silica–alumina‐supported double‐amines are found to exhibit excellent catalysis for 1,3‐dinitroalkane synthesis from various aldehydes with nitromethane. A cooperative catalytic mechanism on the solid surface for this efficient synthesis is proposed.
doi_str_mv 10.1002/anie.200802515
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source Wiley Online Library Journals Frontfile Complete
subjects cooperative effects
CC coupling
immobilization
nitroalkanes
supported catalysts
title Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surfaces for One-Pot C----C Bond Forming Reactions
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