Insight into the Inversion Mechanism of an Inverse Polymer Emulsion
A study of the mechanism of inversion of inverse polymer emulsions showed that the likely key step in the inversion process is the swelling of polymer particles caused by added water diffusing through the oil phase. Therefore, we propose that inversion occurs as a result of polymer particle crowding...
Gespeichert in:
Veröffentlicht in: | Langmuir 2008-11, Vol.24 (22), p.12727-12729 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 12729 |
---|---|
container_issue | 22 |
container_start_page | 12727 |
container_title | Langmuir |
container_volume | 24 |
creator | Gelman, Robert A Harrington, John C Vaynberg, K. Abe |
description | A study of the mechanism of inversion of inverse polymer emulsions showed that the likely key step in the inversion process is the swelling of polymer particles caused by added water diffusing through the oil phase. Therefore, we propose that inversion occurs as a result of polymer particle crowding caused by water diffusion and subsequent droplet rupture that results in the release of the polymer into the water phase. |
doi_str_mv | 10.1021/la8013656 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_69779706</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>69779706</sourcerecordid><originalsourceid>FETCH-LOGICAL-a381t-b271814ab0f5ae31bb8b586824d09785209590c8256eac71fbfd46460e697c723</originalsourceid><addsrcrecordid>eNpt0DtPwzAUBWALgWgpDPwBlAUkhsB1HL9GVPGoVEQFZbYc16EpiVPsBNF_T6pGZWG6w_10dHQQOsdwgyHBt6UWgAmj7AANMU0gpiLhh2gIPCUxTxkZoJMQVgAgSSqP0QALSaQAPkTjiQvFx7KJCtfUUbO00cR9Wx-K2kXP1iy1K0IV1XmkXf-x0awuN5X10X3Vllt4io5yXQZ71t8Ren-4n4-f4unL42R8N401EbiJs4RjgVOdQU61JTjLREYFE0m6AMlF11tSCUYklFltOM6zfJGylIFlkhuekBG62uWuff3V2tCoqgjGlqV2tm6D6hiXHFgHr3fQ-DoEb3O19kWl_UZhUNvF1H6xzl70oW1W2cWf7CfqwGUPdDC6zL12pgh7l4BgEui2XbxzRWjsz_6v_adinHCq5rM3BQSPBXkg6vUvV5ugVnXrXbfdPwV_AZ7di7Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>69779706</pqid></control><display><type>article</type><title>Insight into the Inversion Mechanism of an Inverse Polymer Emulsion</title><source>American Chemical Society (ACS) Journals</source><creator>Gelman, Robert A ; Harrington, John C ; Vaynberg, K. Abe</creator><creatorcontrib>Gelman, Robert A ; Harrington, John C ; Vaynberg, K. Abe</creatorcontrib><description>A study of the mechanism of inversion of inverse polymer emulsions showed that the likely key step in the inversion process is the swelling of polymer particles caused by added water diffusing through the oil phase. Therefore, we propose that inversion occurs as a result of polymer particle crowding caused by water diffusion and subsequent droplet rupture that results in the release of the polymer into the water phase.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la8013656</identifier><identifier>PMID: 18939807</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Emulsions. Microemulsions. Foams ; Exact sciences and technology ; General and physical chemistry ; Surface physical chemistry</subject><ispartof>Langmuir, 2008-11, Vol.24 (22), p.12727-12729</ispartof><rights>Copyright © 2008 American Chemical Society</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a381t-b271814ab0f5ae31bb8b586824d09785209590c8256eac71fbfd46460e697c723</citedby><cites>FETCH-LOGICAL-a381t-b271814ab0f5ae31bb8b586824d09785209590c8256eac71fbfd46460e697c723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la8013656$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la8013656$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2756,27067,27915,27916,56729,56779</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20869052$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18939807$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gelman, Robert A</creatorcontrib><creatorcontrib>Harrington, John C</creatorcontrib><creatorcontrib>Vaynberg, K. Abe</creatorcontrib><title>Insight into the Inversion Mechanism of an Inverse Polymer Emulsion</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>A study of the mechanism of inversion of inverse polymer emulsions showed that the likely key step in the inversion process is the swelling of polymer particles caused by added water diffusing through the oil phase. Therefore, we propose that inversion occurs as a result of polymer particle crowding caused by water diffusion and subsequent droplet rupture that results in the release of the polymer into the water phase.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Emulsions. Microemulsions. Foams</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Surface physical chemistry</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNpt0DtPwzAUBWALgWgpDPwBlAUkhsB1HL9GVPGoVEQFZbYc16EpiVPsBNF_T6pGZWG6w_10dHQQOsdwgyHBt6UWgAmj7AANMU0gpiLhh2gIPCUxTxkZoJMQVgAgSSqP0QALSaQAPkTjiQvFx7KJCtfUUbO00cR9Wx-K2kXP1iy1K0IV1XmkXf-x0awuN5X10X3Vllt4io5yXQZ71t8Ren-4n4-f4unL42R8N401EbiJs4RjgVOdQU61JTjLREYFE0m6AMlF11tSCUYklFltOM6zfJGylIFlkhuekBG62uWuff3V2tCoqgjGlqV2tm6D6hiXHFgHr3fQ-DoEb3O19kWl_UZhUNvF1H6xzl70oW1W2cWf7CfqwGUPdDC6zL12pgh7l4BgEui2XbxzRWjsz_6v_adinHCq5rM3BQSPBXkg6vUvV5ugVnXrXbfdPwV_AZ7di7Q</recordid><startdate>20081118</startdate><enddate>20081118</enddate><creator>Gelman, Robert A</creator><creator>Harrington, John C</creator><creator>Vaynberg, K. Abe</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20081118</creationdate><title>Insight into the Inversion Mechanism of an Inverse Polymer Emulsion</title><author>Gelman, Robert A ; Harrington, John C ; Vaynberg, K. Abe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a381t-b271814ab0f5ae31bb8b586824d09785209590c8256eac71fbfd46460e697c723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Emulsions. Microemulsions. Foams</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Surface physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gelman, Robert A</creatorcontrib><creatorcontrib>Harrington, John C</creatorcontrib><creatorcontrib>Vaynberg, K. Abe</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gelman, Robert A</au><au>Harrington, John C</au><au>Vaynberg, K. Abe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Insight into the Inversion Mechanism of an Inverse Polymer Emulsion</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2008-11-18</date><risdate>2008</risdate><volume>24</volume><issue>22</issue><spage>12727</spage><epage>12729</epage><pages>12727-12729</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>A study of the mechanism of inversion of inverse polymer emulsions showed that the likely key step in the inversion process is the swelling of polymer particles caused by added water diffusing through the oil phase. Therefore, we propose that inversion occurs as a result of polymer particle crowding caused by water diffusion and subsequent droplet rupture that results in the release of the polymer into the water phase.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>18939807</pmid><doi>10.1021/la8013656</doi><tpages>3</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0743-7463 |
ispartof | Langmuir, 2008-11, Vol.24 (22), p.12727-12729 |
issn | 0743-7463 1520-5827 |
language | eng |
recordid | cdi_proquest_miscellaneous_69779706 |
source | American Chemical Society (ACS) Journals |
subjects | Chemistry Colloidal state and disperse state Emulsions. Microemulsions. Foams Exact sciences and technology General and physical chemistry Surface physical chemistry |
title | Insight into the Inversion Mechanism of an Inverse Polymer Emulsion |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T19%3A08%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Insight%20into%20the%20Inversion%20Mechanism%20of%20an%20Inverse%20Polymer%20Emulsion&rft.jtitle=Langmuir&rft.au=Gelman,%20Robert%20A&rft.date=2008-11-18&rft.volume=24&rft.issue=22&rft.spage=12727&rft.epage=12729&rft.pages=12727-12729&rft.issn=0743-7463&rft.eissn=1520-5827&rft.coden=LANGD5&rft_id=info:doi/10.1021/la8013656&rft_dat=%3Cproquest_cross%3E69779706%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=69779706&rft_id=info:pmid/18939807&rfr_iscdi=true |