Shape-Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure-Functionality Relationships in Electrocatalysis
Star performance: The shape and surface structure of star‐shaped gold nanoparticles (NPs) bounded by (331) and vicinal high‐index facets, now synthesized for the first time, can be tuned by varying the water content in the deep eutetic solvent. The results confirm that star‐shaped Au NPs exhibit sup...
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Veröffentlicht in: | Angewandte Chemie (International ed.) 2008-01, Vol.47 (47), p.9100-9103 |
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creator | Liao, Hong-Gang Jiang, Yan-Xia Zhou, Zhi-You Chen, Sheng-Pei Sun, Shi-Gang |
description | Star performance: The shape and surface structure of star‐shaped gold nanoparticles (NPs) bounded by (331) and vicinal high‐index facets, now synthesized for the first time, can be tuned by varying the water content in the deep eutetic solvent. The results confirm that star‐shaped Au NPs exhibit superior activity for electrocatalytic reduction of H2O2. The ability to tune the shape offers insight into structure–functionality relationships. |
doi_str_mv | 10.1002/anie.200803202 |
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The ability to tune the shape offers insight into structure–functionality relationships.</description><subject>deep eutectic solvents</subject><subject>electrocatalysis</subject><subject>reduction</subject><subject>shape‐controlled synthesis</subject><subject>structure‐activity relationships</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkUtv1DAURiNERR-wZQlescvgxyR2ltUwfUhVKzXt2rrj3DBGnjjYDii_gz-MpzMCdqz80PnOlf0VxXtGF4xS_hkGiwtOqaKCU_6qOGMVZ6WQUrzO-6UQpVQVOy3OY_yWeaVo_aY4ZarhVdXws-JXu4URy5UfUvDOYUfaeUhbjDYS35Nr7zpyD4MfISRrHEZiB_IFcSTrKaHJd6T17gcOKZLeB9KmqbP4km1TmEyaApZX05BJP4CzaSaP6GB_ils7vujWLouCN5DAzXnw2-KkBxfx3XG9KJ6v1k-rm_Lu4fp2dXlXmvwuXipJlWGyppRuuAGADShQCIqzXhmharOk0FW8BoSlXLKey2pPVxshK6iMuCg-Hbxj8N8njEnvbDToHAzop6jrRsqaU5XBxQE0wccYsNdjsDsIs2ZU72vQ-xr0nxpy4MPRPG122P3Fj_-egeYA_LQO5__o9OX97fpf-cdDtgev4WuwUT-3nDJBWXY3rBa_AScfoKo</recordid><startdate>20080101</startdate><enddate>20080101</enddate><creator>Liao, Hong-Gang</creator><creator>Jiang, Yan-Xia</creator><creator>Zhou, Zhi-You</creator><creator>Chen, Sheng-Pei</creator><creator>Sun, Shi-Gang</creator><general>Wiley-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20080101</creationdate><title>Shape-Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure-Functionality Relationships in Electrocatalysis</title><author>Liao, Hong-Gang ; Jiang, Yan-Xia ; Zhou, Zhi-You ; Chen, Sheng-Pei ; Sun, Shi-Gang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4332-8708c176000b2caaaba8a8ea821f8c386c40ad526aea4741f27576005b375a5c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>deep eutectic solvents</topic><topic>electrocatalysis</topic><topic>reduction</topic><topic>shape‐controlled synthesis</topic><topic>structure‐activity relationships</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liao, Hong-Gang</creatorcontrib><creatorcontrib>Jiang, Yan-Xia</creatorcontrib><creatorcontrib>Zhou, Zhi-You</creatorcontrib><creatorcontrib>Chen, Sheng-Pei</creatorcontrib><creatorcontrib>Sun, Shi-Gang</creatorcontrib><collection>AGRIS</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liao, Hong-Gang</au><au>Jiang, Yan-Xia</au><au>Zhou, Zhi-You</au><au>Chen, Sheng-Pei</au><au>Sun, Shi-Gang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Shape-Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure-Functionality Relationships in Electrocatalysis</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2008-01-01</date><risdate>2008</risdate><volume>47</volume><issue>47</issue><spage>9100</spage><epage>9103</epage><pages>9100-9103</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Star performance: The shape and surface structure of star‐shaped gold nanoparticles (NPs) bounded by (331) and vicinal high‐index facets, now synthesized for the first time, can be tuned by varying the water content in the deep eutetic solvent. The results confirm that star‐shaped Au NPs exhibit superior activity for electrocatalytic reduction of H2O2. The ability to tune the shape offers insight into structure–functionality relationships.</abstract><cop>Weinheim</cop><pub>Wiley-VCH Verlag</pub><pmid>18925592</pmid><doi>10.1002/anie.200803202</doi><tpages>4</tpages></addata></record> |
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subjects | deep eutectic solvents electrocatalysis reduction shape‐controlled synthesis structure‐activity relationships |
title | Shape-Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure-Functionality Relationships in Electrocatalysis |
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