Mechanical Reinforcement of a Supramolecular Hydrogel Comprising an Artificial Glyco-Lipid through Supramolecular Copolymerization

Supramolecular copolymer hydrogels were prepared by mixing 1 and the additives 2–8, and their rheological properties were evaluated. It was found that additive 3 reinforced the mechanical strength of the resultant hydrogel most efficiently, increasing the yield stress of SCH 1+3 about fourfold. The...

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Veröffentlicht in:Macromolecular bioscience 2008-11, Vol.8 (11), p.1019-1025
Hauptverfasser: Ikeda, Masato, Shimizu, Yusuke, Matsumoto, Shinji, Komatsu, Harunobu, Tamaru, Shun-ichi, Takigawa, Toshikazu, Hamachi, Itaru
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container_end_page 1025
container_issue 11
container_start_page 1019
container_title Macromolecular bioscience
container_volume 8
creator Ikeda, Masato
Shimizu, Yusuke
Matsumoto, Shinji
Komatsu, Harunobu
Tamaru, Shun-ichi
Takigawa, Toshikazu
Hamachi, Itaru
description Supramolecular copolymer hydrogels were prepared by mixing 1 and the additives 2–8, and their rheological properties were evaluated. It was found that additive 3 reinforced the mechanical strength of the resultant hydrogel most efficiently, increasing the yield stress of SCH 1+3 about fourfold. The optimal mixing between the glyco‐lipid hydrogelator 1 and the additive 3 sufficiently enhanced the mechanical strength of the resultant SCH, which improved the handling of the SH on the large scale. These results indicate that supramolecular copolymerization can provide the supramolecular hydrogel with desired properties and/or functions.
doi_str_mv 10.1002/mabi.200800061
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source MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects Biomimetic Materials
Glycolipids
hydrogels
Hydrogels - chemical synthesis
Hydrogels - chemistry
Indicators and Reagents
mechanical strength
Mechanics
Rheology
supramolecular chemistry
title Mechanical Reinforcement of a Supramolecular Hydrogel Comprising an Artificial Glyco-Lipid through Supramolecular Copolymerization
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