Mechanical Reinforcement of a Supramolecular Hydrogel Comprising an Artificial Glyco-Lipid through Supramolecular Copolymerization
Supramolecular copolymer hydrogels were prepared by mixing 1 and the additives 2–8, and their rheological properties were evaluated. It was found that additive 3 reinforced the mechanical strength of the resultant hydrogel most efficiently, increasing the yield stress of SCH 1+3 about fourfold. The...
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Veröffentlicht in: | Macromolecular bioscience 2008-11, Vol.8 (11), p.1019-1025 |
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creator | Ikeda, Masato Shimizu, Yusuke Matsumoto, Shinji Komatsu, Harunobu Tamaru, Shun-ichi Takigawa, Toshikazu Hamachi, Itaru |
description | Supramolecular copolymer hydrogels were prepared by mixing 1 and the additives 2–8, and their rheological properties were evaluated. It was found that additive 3 reinforced the mechanical strength of the resultant hydrogel most efficiently, increasing the yield stress of SCH 1+3 about fourfold. The optimal mixing between the glyco‐lipid hydrogelator 1 and the additive 3 sufficiently enhanced the mechanical strength of the resultant SCH, which improved the handling of the SH on the large scale. These results indicate that supramolecular copolymerization can provide the supramolecular hydrogel with desired properties and/or functions. |
doi_str_mv | 10.1002/mabi.200800061 |
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These results indicate that supramolecular copolymerization can provide the supramolecular hydrogel with desired properties and/or functions.</description><subject>Biomimetic Materials</subject><subject>Glycolipids</subject><subject>hydrogels</subject><subject>Hydrogels - chemical synthesis</subject><subject>Hydrogels - chemistry</subject><subject>Indicators and Reagents</subject><subject>mechanical strength</subject><subject>Mechanics</subject><subject>Rheology</subject><subject>supramolecular chemistry</subject><issn>1616-5187</issn><issn>1616-5195</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU2P0zAQhi0EYpeFK0eUE7cUO4m_jt0KurtqF4nl42i5zrg1OHGwE0H2uL-cVK0K4rKnmcPzPiPNi9BrgmcE4-JdozduVmAsMMaMPEHnhBGWUyLp09Mu-Bl6kdJ3jAkXsniOzoignJVSnKOHNZidbp3RPvsErrUhGmig7bNgM53dDV3UTfBgBq9jdjXWMWzBZ4vQdNEl124z3Wbz2DvrjJscSz-akK9c5-qs38UwbHf_SxahC35sILp73bvQvkTPrPYJXh3nBfry4f3nxVW--ri8XsxXuaFFQfINY2yaVBaFtFJwiy2rQW9wVVXa6IIKKKnVNceGmrqsTF1IVoEuYf8oK8oL9Pbg7WL4OUDqVeOSAe91C2FIiknOqRSPgyUVgpSYT-DsAJoYUopg1fSURsdREaz2V9W-HnWqZwq8OZqHTQP1X_zYxwTIA_DLeRgf0an1_PL6X3l-yLrUw-9TVscfivGSU_Xtdqku1wLf3N7cqa_lH8OCris</recordid><startdate>20081110</startdate><enddate>20081110</enddate><creator>Ikeda, Masato</creator><creator>Shimizu, Yusuke</creator><creator>Matsumoto, Shinji</creator><creator>Komatsu, Harunobu</creator><creator>Tamaru, Shun-ichi</creator><creator>Takigawa, Toshikazu</creator><creator>Hamachi, Itaru</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20081110</creationdate><title>Mechanical Reinforcement of a Supramolecular Hydrogel Comprising an Artificial Glyco-Lipid through Supramolecular Copolymerization</title><author>Ikeda, Masato ; Shimizu, Yusuke ; Matsumoto, Shinji ; Komatsu, Harunobu ; Tamaru, Shun-ichi ; Takigawa, Toshikazu ; Hamachi, Itaru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5221-b66622159229f987f0f6deab0444aca258e35fad70c5cd34cd2964ea3e1002f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Biomimetic Materials</topic><topic>Glycolipids</topic><topic>hydrogels</topic><topic>Hydrogels - chemical synthesis</topic><topic>Hydrogels - chemistry</topic><topic>Indicators and Reagents</topic><topic>mechanical strength</topic><topic>Mechanics</topic><topic>Rheology</topic><topic>supramolecular chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ikeda, Masato</creatorcontrib><creatorcontrib>Shimizu, Yusuke</creatorcontrib><creatorcontrib>Matsumoto, Shinji</creatorcontrib><creatorcontrib>Komatsu, Harunobu</creatorcontrib><creatorcontrib>Tamaru, Shun-ichi</creatorcontrib><creatorcontrib>Takigawa, Toshikazu</creatorcontrib><creatorcontrib>Hamachi, Itaru</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Macromolecular bioscience</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ikeda, Masato</au><au>Shimizu, Yusuke</au><au>Matsumoto, Shinji</au><au>Komatsu, Harunobu</au><au>Tamaru, Shun-ichi</au><au>Takigawa, Toshikazu</au><au>Hamachi, Itaru</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanical Reinforcement of a Supramolecular Hydrogel Comprising an Artificial Glyco-Lipid through Supramolecular Copolymerization</atitle><jtitle>Macromolecular bioscience</jtitle><addtitle>Macromol. 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subjects | Biomimetic Materials Glycolipids hydrogels Hydrogels - chemical synthesis Hydrogels - chemistry Indicators and Reagents mechanical strength Mechanics Rheology supramolecular chemistry |
title | Mechanical Reinforcement of a Supramolecular Hydrogel Comprising an Artificial Glyco-Lipid through Supramolecular Copolymerization |
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