Carbene-Stabilized Diphosphorus
The potassium graphite reduction of L:PCl3 leads to the formation of carbene-stabilized diphosphorus molecules, L:P−P:L, 1 (L: = :C{N(2,6-Pr i 2C6H3)CH}2) and 2 (L: = :C{N(2,4,6-Me3C6H2)CH}2), respectively. The nature of the bonding in 1 and 2 was delineated by DFT computations.
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| Veröffentlicht in: | Journal of the American Chemical Society 2008-11, Vol.130 (45), p.14970-14971 |
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| container_end_page | 14971 |
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| container_issue | 45 |
| container_start_page | 14970 |
| container_title | Journal of the American Chemical Society |
| container_volume | 130 |
| creator | Wang, Yuzhong Xie, Yaoming Wei, Pingrong King, R. Bruce Schaefer, III, Henry F Schleyer, Paul v. R Robinson, Gregory H |
| description | The potassium graphite reduction of L:PCl3 leads to the formation of carbene-stabilized diphosphorus molecules, L:P−P:L, 1 (L: = :C{N(2,6-Pr i 2C6H3)CH}2) and 2 (L: = :C{N(2,4,6-Me3C6H2)CH}2), respectively. The nature of the bonding in 1 and 2 was delineated by DFT computations. |
| doi_str_mv | 10.1021/ja807828t |
| format | Article |
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The nature of the bonding in 1 and 2 was delineated by DFT computations.</description><subject>Imidazoles - chemistry</subject><subject>Imidazolidines - chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Methane - analogs & derivatives</subject><subject>Methane - chemistry</subject><subject>Models, Molecular</subject><subject>Phosphorus - chemistry</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0E1LwzAYB_AgipvTg19AvSh4iObtSdKjzFcYKKyCeAlJl2Fnt86kBfXTG2mZFyEhPMmPJ8kfoUNKLihh9HJhNVGa6WYLDSkwgoEyuY2GhBCGlZZ8gPZiXKRSME130YDqjCshyRAdj21wfuXxtLGurMpvPzu5LtdvdUwztHEf7cxtFf1Bv47Q8-1NPr7Hk8e7h_HVBFsOtMGU0owBaC890eC0LgSAElpzL7lOe6kE5yyXasaVVHwuINnMgc3S4HyEzrq-61B_tD42ZlnGwleVXfm6jUZmCkAwluB5B4tQxxj83KxDubThy1BiftMwmzSSPeqbtm7pZ3-y_34CuANlbPzn5tyGd5PeqMDkT1NDppAr8QrmJfnTztsimkXdhlXK5J-LfwAbanJC</recordid><startdate>20081112</startdate><enddate>20081112</enddate><creator>Wang, Yuzhong</creator><creator>Xie, Yaoming</creator><creator>Wei, Pingrong</creator><creator>King, R. 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| source | MEDLINE; American Chemical Society Journals |
| subjects | Imidazoles - chemistry Imidazolidines - chemistry Magnetic Resonance Spectroscopy Methane - analogs & derivatives Methane - chemistry Models, Molecular Phosphorus - chemistry |
| title | Carbene-Stabilized Diphosphorus |
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