Allene as the Parent Substrate in Zinc-Mediated Biomimetic Hydration Reactions of Cumulenes

The aim of our present investigation is to unravel the general mode of biomimetic activation of a wide variety of cumulenes by carbonic anhydrase (CA) models. Carbonic anhydrases allow the specific recognition, activation and transfer not only of CO2 but also of heteroallenes XCY such as the polar...

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Veröffentlicht in:	Journal of organic chemistry 2008-11, Vol.73 (21), p.8265-8278
Hauptverfasser:	Jahn, Burkhard O, Eger, Wilhelm A, Anders, Ernst
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkadienes - chemistry Biomimetics - methods Carbonic Anhydrases - chemistry Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Kinetics and mechanisms Models, Molecular Models, Theoretical Organic chemistry Polyenes - chemistry Reactivity and mechanisms Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Thermodynamics Zinc
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