Ternary complexes of palladium (II) with levamisole and l-amino acids
The complexes of general formula [(LMS) 2Pd(amino acid)]Cl with LMS = levamisole, and amino acid = l-alanine, l-phenylglycine, l-phenylalanine, l-valine, l-methionine, and l-proline, were synthesized by the interaction of [(LMS) 2PdCl 2] with the sodium salts of l-amino acids. The newly synthesized...
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| Veröffentlicht in: | Journal of inorganic biochemistry 1999, Vol.73 (1), p.109-115 |
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| creator | Nijasure, A.M. Joshi, V.N. Sawant, A.D. |
| description | The complexes of general formula [(LMS)
2Pd(amino acid)]Cl with LMS = levamisole, and amino acid =
l-alanine,
l-phenylglycine,
l-phenylalanine,
l-valine,
l-methionine, and
l-proline, were synthesized by the interaction of [(LMS)
2PdCl
2] with the sodium salts of
l-amino acids. The newly synthesized complexes are characterized by elemental analysis, conductivity, magnetic susceptibility, optical rotation measurements, and UV-Vis, IR and
13C NMR spectral data. Levamisole is coordinated to palladium via the N-7 nitrogen and the amino acids through the amino nitrogen and carboxylate oxygen, except for
l-methionine which binds the metal via nitrogen and sulfur atoms. Optically active [(LMS)
2Pd(amino acid)]Cl complexes are obtained when
l-amino acids or
d,l-amino acids are used for the synthesis of these complexes.
l-Methionine and
l-proline complexes induce new cell forms in Baker's yeast (
Saccharomyces cerevisiae) cells. |
| doi_str_mv | 10.1016/S0162-0134(99)00008-2 |
| format | Article |
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2Pd(amino acid)]Cl with LMS = levamisole, and amino acid =
l-alanine,
l-phenylglycine,
l-phenylalanine,
l-valine,
l-methionine, and
l-proline, were synthesized by the interaction of [(LMS)
2PdCl
2] with the sodium salts of
l-amino acids. The newly synthesized complexes are characterized by elemental analysis, conductivity, magnetic susceptibility, optical rotation measurements, and UV-Vis, IR and
13C NMR spectral data. Levamisole is coordinated to palladium via the N-7 nitrogen and the amino acids through the amino nitrogen and carboxylate oxygen, except for
l-methionine which binds the metal via nitrogen and sulfur atoms. Optically active [(LMS)
2Pd(amino acid)]Cl complexes are obtained when
l-amino acids or
d,l-amino acids are used for the synthesis of these complexes.
l-Methionine and
l-proline complexes induce new cell forms in Baker's yeast (
Saccharomyces cerevisiae) cells.</description><identifier>ISSN: 0162-0134</identifier><identifier>EISSN: 1873-3344</identifier><identifier>DOI: 10.1016/S0162-0134(99)00008-2</identifier><identifier>PMID: 10212998</identifier><language>eng</language><publisher>United States: Elsevier Inc</publisher><subject>Adjuvants, Immunologic - chemistry ; Adjuvants, Immunologic - pharmacology ; Amino Acids - chemistry ; Antineoplastic Agents - chemistry ; Antineoplastic Agents - pharmacology ; l-Amino acids ; Levamisole ; Levamisole - chemistry ; Levamisole - pharmacology ; Magnetic Resonance Spectroscopy ; Mass Spectrometry ; Molecular Structure ; Palladium (II) ; Palladium - chemistry ; Palladium - pharmacology ; Saccharomyces cerevisiae - drug effects</subject><ispartof>Journal of inorganic biochemistry, 1999, Vol.73 (1), p.109-115</ispartof><rights>1999 Elsevier Science Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-d6628710ac9b34fa3c0471818fc4dda5769ef051b44bc285bc5947ca49cc2c833</citedby><cites>FETCH-LOGICAL-c361t-d6628710ac9b34fa3c0471818fc4dda5769ef051b44bc285bc5947ca49cc2c833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0162013499000082$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,4009,27902,27903,27904,65309</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10212998$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nijasure, A.M.</creatorcontrib><creatorcontrib>Joshi, V.N.</creatorcontrib><creatorcontrib>Sawant, A.D.</creatorcontrib><title>Ternary complexes of palladium (II) with levamisole and l-amino acids</title><title>Journal of inorganic biochemistry</title><addtitle>J Inorg Biochem</addtitle><description>The complexes of general formula [(LMS)
2Pd(amino acid)]Cl with LMS = levamisole, and amino acid =
l-alanine,
l-phenylglycine,
l-phenylalanine,
l-valine,
l-methionine, and
l-proline, were synthesized by the interaction of [(LMS)
2PdCl
2] with the sodium salts of
l-amino acids. The newly synthesized complexes are characterized by elemental analysis, conductivity, magnetic susceptibility, optical rotation measurements, and UV-Vis, IR and
13C NMR spectral data. Levamisole is coordinated to palladium via the N-7 nitrogen and the amino acids through the amino nitrogen and carboxylate oxygen, except for
l-methionine which binds the metal via nitrogen and sulfur atoms. Optically active [(LMS)
2Pd(amino acid)]Cl complexes are obtained when
l-amino acids or
d,l-amino acids are used for the synthesis of these complexes.
l-Methionine and
l-proline complexes induce new cell forms in Baker's yeast (
Saccharomyces cerevisiae) cells.</description><subject>Adjuvants, Immunologic - chemistry</subject><subject>Adjuvants, Immunologic - pharmacology</subject><subject>Amino Acids - chemistry</subject><subject>Antineoplastic Agents - chemistry</subject><subject>Antineoplastic Agents - pharmacology</subject><subject>l-Amino acids</subject><subject>Levamisole</subject><subject>Levamisole - chemistry</subject><subject>Levamisole - pharmacology</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Mass Spectrometry</subject><subject>Molecular Structure</subject><subject>Palladium (II)</subject><subject>Palladium - chemistry</subject><subject>Palladium - pharmacology</subject><subject>Saccharomyces cerevisiae - drug effects</subject><issn>0162-0134</issn><issn>1873-3344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkMlKBDEQQIMoOo5-gpKTjIfWbL3kJDK4DAge1HNIV6ox0pudnlH_3miLeDOHCgWvtkfIEWdnnPHs_CEGkTAu1ULrUxZfkYgtMuNFLhMpldoms19kj-yH8BKZNFX5LtnjTHChdTEjV484tHb4oNA1fY3vGGhX0d7WtXV-3dDFanVK3_z4TGvc2MaHrkZqW0frJGZtRy14Fw7ITmXrgIc__5w8XV89Lm-Tu_ub1fLyLgGZ8TFxWSaKnDMLupSqshKYynnBiwqUczbNM40VS3mpVAmiSEtItcrBKg0goJByTk6mvv3Qva4xjCZuBBiXbbFbB5PpnItM8gimEwhDF8KAlekH38Q7DWfmy5_59me-5Bitzbc_I2Ld8c-Addmg-1M1CYvAxQRgPHPjcTABPLaAzg8Io3Gd_2fEJ6x0fj0</recordid><startdate>1999</startdate><enddate>1999</enddate><creator>Nijasure, A.M.</creator><creator>Joshi, V.N.</creator><creator>Sawant, A.D.</creator><general>Elsevier Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>1999</creationdate><title>Ternary complexes of palladium (II) with levamisole and l-amino acids</title><author>Nijasure, A.M. ; Joshi, V.N. ; Sawant, A.D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-d6628710ac9b34fa3c0471818fc4dda5769ef051b44bc285bc5947ca49cc2c833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Adjuvants, Immunologic - chemistry</topic><topic>Adjuvants, Immunologic - pharmacology</topic><topic>Amino Acids - chemistry</topic><topic>Antineoplastic Agents - chemistry</topic><topic>Antineoplastic Agents - pharmacology</topic><topic>l-Amino acids</topic><topic>Levamisole</topic><topic>Levamisole - chemistry</topic><topic>Levamisole - pharmacology</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Mass Spectrometry</topic><topic>Molecular Structure</topic><topic>Palladium (II)</topic><topic>Palladium - chemistry</topic><topic>Palladium - pharmacology</topic><topic>Saccharomyces cerevisiae - drug effects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nijasure, A.M.</creatorcontrib><creatorcontrib>Joshi, V.N.</creatorcontrib><creatorcontrib>Sawant, A.D.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of inorganic biochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nijasure, A.M.</au><au>Joshi, V.N.</au><au>Sawant, A.D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ternary complexes of palladium (II) with levamisole and l-amino acids</atitle><jtitle>Journal of inorganic biochemistry</jtitle><addtitle>J Inorg Biochem</addtitle><date>1999</date><risdate>1999</risdate><volume>73</volume><issue>1</issue><spage>109</spage><epage>115</epage><pages>109-115</pages><issn>0162-0134</issn><eissn>1873-3344</eissn><abstract>The complexes of general formula [(LMS)
2Pd(amino acid)]Cl with LMS = levamisole, and amino acid =
l-alanine,
l-phenylglycine,
l-phenylalanine,
l-valine,
l-methionine, and
l-proline, were synthesized by the interaction of [(LMS)
2PdCl
2] with the sodium salts of
l-amino acids. The newly synthesized complexes are characterized by elemental analysis, conductivity, magnetic susceptibility, optical rotation measurements, and UV-Vis, IR and
13C NMR spectral data. Levamisole is coordinated to palladium via the N-7 nitrogen and the amino acids through the amino nitrogen and carboxylate oxygen, except for
l-methionine which binds the metal via nitrogen and sulfur atoms. Optically active [(LMS)
2Pd(amino acid)]Cl complexes are obtained when
l-amino acids or
d,l-amino acids are used for the synthesis of these complexes.
l-Methionine and
l-proline complexes induce new cell forms in Baker's yeast (
Saccharomyces cerevisiae) cells.</abstract><cop>United States</cop><pub>Elsevier Inc</pub><pmid>10212998</pmid><doi>10.1016/S0162-0134(99)00008-2</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of inorganic biochemistry, 1999, Vol.73 (1), p.109-115 |
| issn | 0162-0134 1873-3344 |
| language | eng |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Adjuvants, Immunologic - chemistry Adjuvants, Immunologic - pharmacology Amino Acids - chemistry Antineoplastic Agents - chemistry Antineoplastic Agents - pharmacology l-Amino acids Levamisole Levamisole - chemistry Levamisole - pharmacology Magnetic Resonance Spectroscopy Mass Spectrometry Molecular Structure Palladium (II) Palladium - chemistry Palladium - pharmacology Saccharomyces cerevisiae - drug effects |
| title | Ternary complexes of palladium (II) with levamisole and l-amino acids |
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