Chirality-Controlled and Solvent-Templated Catenation Isomerism in Metal−Organic Frameworks

A family of highly porous homochiral, racemic, and meso metal−organic frameworks (MOFs) were synthesized based on a new elongated tetra-carboxylate ligand and the copper paddle-wheel building units. These MOFs exhibited remarkable catenation isomerism that is controlled by both chirality of the brid...

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Veröffentlicht in:	Journal of the American Chemical Society 2008-10, Vol.130 (42), p.13834-13835
Hauptverfasser:	Ma, Liqing, Lin, Wenbin
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper - chemistry Dimethylformamide - chemistry Ligands Magnetic Resonance Spectroscopy - methods Models, Molecular Molecular Structure Naphthalenes - chemistry Organometallic Compounds - chemistry Powder Diffraction Solvents - chemistry Stereoisomerism Thermogravimetry Water - chemistry
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