Total syntheses of (+/-)-montanin A and (+/-)-teuscorolide

The first total syntheses of (+/-)-montanin A and (+/-)-teuscorolide have been achieved from an advanced precursor previously developed via a Diels-Alder strategy; in the synthetic sequence, the synthesis of montanin A was first accomplished in 8 steps, from which teuscorolide was readily achieved i...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2008-01 (39), p.4720-4722
Hauptverfasser:	Chen, I-Chia, Wu, Yen-Ku, Liu, Hsing-Jang, Zhu, Jiang-Liang
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclization Furans - chemical synthesis Furans - chemistry Molecular Conformation Pentanols - chemistry Spiro Compounds - chemical synthesis Spiro Compounds - chemistry Stereoisomerism
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description	The first total syntheses of (+/-)-montanin A and (+/-)-teuscorolide have been achieved from an advanced precursor previously developed via a Diels-Alder strategy; in the synthetic sequence, the synthesis of montanin A was first accomplished in 8 steps, from which teuscorolide was readily achieved in 2 steps by using a novel furan oxidative cyclization-retro-cyclization process as a key operation.
doi_str_mv	10.1039/b807218c
format	Article
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source	MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Cyclization Furans - chemical synthesis Furans - chemistry Molecular Conformation Pentanols - chemistry Spiro Compounds - chemical synthesis Spiro Compounds - chemistry Stereoisomerism
title	Total syntheses of (+/-)-montanin A and (+/-)-teuscorolide
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