Mechanistically Inspired Catalysts for Enantioselective Desymmetrizations by Olefin Metathesis

In asymmetric olefin metathesis reactions, the addition of halide additives is often required to augment enantioselectivities, despite the fact that the additives result in catalysts with diminished reactivities. The preparation of new chiral Ru‐based catalysts was accomplished by exploiting previou...

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Veröffentlicht in:	Chemistry : a European journal 2008-09, Vol.14 (28), p.8690-8695
Hauptverfasser:	Fournier, Pierre-André, Savoie, Jolaine, Stenne, Brice, Bédard, Marion, Grandbois, Alain, Collins, Shawn K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry asymmetric catalysis Catalysis desymmetrization N-heterocyclic carbenes olefin metathesis ruthenium Stereoisomerism
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