Self-Assembly of L-Cysteinato Trinuclear Cations into Metallosupramolecular Architectures Controlled by Protons, Metal Ions, and Chirality

Complete control: Versatile self‐assembly of the L‐cysteinato CoIIIHgIICoIII trinuclear complex into dimeric, metallohelix, and metallocage structures, which is induced by deprotonation of L‐cysteine carboxyl groups, is reported. Remarkably, the homochiral (ΛLΛL‐CoIIIHgIICoIII)6 metallocage, which e...

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Veröffentlicht in:	Chemistry : a European journal 2008-09, Vol.14 (26), p.7752-7755
Hauptverfasser:	Aridomi, Takashi, Takamura, Keiichi, Igashira-Kamiyama, Asako, Kawamoto, Tatsuya, Konno, Takumi
Format:	Artikel
Sprache:	eng
Schlagworte:	cage compounds cysteine helical structures mercury supramolecular chemistry
Online-Zugang:	Volltext
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