Synthesis of Fused Piperidinones through a Radical-Ionic Cascade

Azabicyclo[4.3.0]nonanes were assembled, from chiral allylsilanes possessing an oxime moiety, using a stereocontrolled formal [2 + 2 + 2] radical-ionic process. The cascade involves the addition of an α-iodoester to the less substituted end of the enoxime which is then followed by a 5-exo-trig cycli...

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