Formation of γ-Lactones through CAN-Mediated Oxidative Cleavage of Hemiketals

The generation of substituted γ-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an α-heteroatom. Formatio...

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Veröffentlicht in:	Journal of organic chemistry 2008-09, Vol.73 (18), p.7409-7412
Hauptverfasser:	Jacobine, Alexander M, Lin, Weimin, Walls, Bethany, Zercher, Charles K
Format:	Artikel
Sprache:	eng
Schlagworte:	4-Butyrolactone - analogs & derivatives 4-Butyrolactone - chemical synthesis 4-Butyrolactone - chemistry Cerium - chemistry Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Ketones - chemistry Lactones - chemical synthesis Lactones - chemistry Molecular Conformation Organic chemistry Oxidation-Reduction Preparations and properties Stereoisomerism
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